Solubilities of isophthalic acid in ternary mixtures of acetic acid + water + benzoic acid were determined by static analytical method. The temperature range was from 292.55 to 372.10 K, the mass ratios of water to acetic acid were 0, 1:9, and 1:4, and the mass fractions of benzoic acid in initial solvent ranged from 0 to 20.1%. The experimental results indicated that solubility of isophthalic acid increased with the introduction of benzoic acid to the binary solvents of acetic acid and water, and that could be explained by Hansen's threedimensional parameters and like-dissolves-like rule. Then the experimental solubilities were correlated by the Non-Random Two Liquids (NRTL) model, and the model parameters were regressed. The values calculated by NRTL model showed good agreement with the experiment data.
Compounds
#
Formula
Name
1
C8H6O4
1,3-benzenedicarboxylic acid
2
C7H6O2
benzoic acid
3
C2H4O2
acetic acid
4
H2O
water
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.