Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measuring the Refractive Index, Density, Viscosity, pH, and Surface Tension of Potassium Thiocyanate (KSCN) Solutions for Refractive Index Matching in Flow Experiments

Agrawal, Yogesh K., Sabbagh, Reza, Sanders, Sean, Nobes, David S.
J. Chem. Eng. Data 2018, 63, 5, 1275-1285
ABSTRACT
Refractive index matching (RIM) methods are widely used in combination with optical flow measurement techniques such as particle image velocimetry and laser Doppler velocimetry to investigate fluid flows. In applying RIM, matching the refractive indices of the fluid and solid eliminates the problem of refraction/reflection at the solid-liquid interface. An experimental analysis of the effects of salt concentration and temperature on the refractive index of potassium thiocyanate (KSCN) solutions is conducted to quantify its performance as a RIM solution that is used in flow experiments. This enables the researchers to control the refractive index of the test medium under different test conditions by manipulating the KSCN concentration in the solution. Empirical correlations are developed by fitting the refractive index results, which highlight a non-linear dependency
Compounds
# Formula Name
1 CKNS potassium thiocyanate
2 INa sodium iodide
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 3
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 210
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Buoyancy - hydrostatic balance
  • 12
  • POMD
  • 1
  • 3
  • Viscosity, Pa*s ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 12
  • POMD
  • 1
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Wilhelmi plate
  • 11
  • POMD
  • 1
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 1
  • POMD
  • 2
  • 3
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Titration method
  • 1
  • POMD
  • 2
  • 3
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 30