Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurements of Saturation Pressures for Trifluoroethene (R1123) and 3,3,3-Trifluoropropene (R1243zf)

Higashi, Yukihiro, Sakoda, Naoya, Islam, Md. Amirul, Takata, Yasuyuki, Koyama, Shigeru, Akasaka, Ryo
J. Chem. Eng. Data 2018, 63, 2, 417-421
ABSTRACT
Saturation pressures for new low-GWP refrigerants: trifluoroethene (R1123: CF2=CHF) and 3,3,3-trifluoropropene (R1243zf : CF3CH=CH2) were measured by the isochoric method for temperatures between 278 K and 377 K. Temperature was measured with a 25 greater than standard platinum resistance thermometer on ITS-90. Pressure was measured with a digital quartz pressure transducer. The experimental uncertainties in temperature and pressure are estimated to be 5 mK and 1 kPa (k = 2), respectively. New saturation-pressure correlations for the refrigerants have been formulated based on the present saturation-pressure data. The critical pressures of R1123 and R1243zf were also determined.
Compounds
# Formula Name
1 C2HF3 trifluoroethene
2 C3H3F3 1,1,1-trifluoro-2-propene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 27
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 20