Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Phase Equilibrium of Three Binary Mixtures Containing NO and Components Present in Ambient Air

Zhang, Fan, Ahmar, Elise El, Valtz, Alain, Boonaert, Eric, Coquelet, Christophe, Chapoy, Antonin
J. Chem. Eng. Data 2018, 63, 4, 1021-1026
ABSTRACT
Air contains impurities, which must be removed before its transformation and utilization. In the present work, new isothermal Vapor-Liquid Equilibrium (VLE) data are reported for three binary systems containing NO with (CO, N2 or Ar) at different temperatures (between 105 and 146 K) and pressures up to 4 MPa. The compositions of the coexisting phases were experimentally determined using an apparatus based on the "static-analytic" method. The Peng-Robinson Equation of State combined with different mixing rules (classical, WongSandler and Huron-Vidal) were used to represent the phase diagram (P, x, y).
Compounds
# Formula Name
1 Ar argon
2 N2 nitrogen
3 CO carbon monoxide
4 NO nitrogen oxide (NO)
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 2
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 2
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 3
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Crystal
  • Temperature, K; Crystal
  • Crystal
  • Gas
  • Closed cell (Static) method
  • 1
  • POMD
  • 1
  • 4
  • Vapor or sublimation pressure, kPa ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Closed cell (Static) method
  • 21
  • POMD
  • 1
  • 4
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 21
  • POMD
  • 3
  • 4
  • Vapor or sublimation pressure, kPa ; Gas
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Closed cell (Static) method
  • 28
  • POMD
  • 3
  • 4
  • Mole fraction - 3 ; Gas
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 28
  • POMD
  • 2
  • 4
  • Vapor or sublimation pressure, kPa ; Gas
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Closed cell (Static) method
  • 21
  • POMD
  • 2
  • 4
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 21
  • POMD
  • 2
  • 4
  • Mole fraction - 2 ; Gas
  • Pressure, kPa; Gas
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Chromatography
  • 2