Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement and Correlation of the Solubilities of Oxygen, Nitrogen, and Carbon Dioxide in JP-10

Liu, Xiangyang, Liu, Siqi, Bai, Lihang, He, Maogang
J. Chem. Eng. Data 2017, 62, 11, 3998-4005
ABSTRACT
New experimental solubility data of nitrogen, oxygen, and carbon dioxide in JP-10 (exo-tetrahydrodicyclopentadiene) in the temperature range from 293K to 343K in the intervals of 10 K and in the pressure range from 0.5 MPa to 7.5 MPa were reported. The relative expanded uncertainty of solubility measurement is estimated to be less than 4 % with a level of confidence of 95 %. The solubility order of the three gases in JP-10 in the studied temperature and pressure range is: carbon dioxide greater than oxygen greater than nitrogen. The Henry s constants and the thermodynamic properties of solvation were calculated from the solubility data. A modified KK equation was used to represent the experimental data with AARD less than 1.9 %.
Compounds
# Formula Name
1 C10H16 exo-tetrahydrodicyclopentadiene
2 CO2 carbon dioxide
3 N2 nitrogen
4 O2 oxygen
5 C12H19F6N3O4S2 1-hexyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 5
  • Mole fraction - 2 ; Liquid - 2
  • Temperature, K; Liquid - 2
  • Pressure, kPa; Liquid - 2
  • Liquid - 2
  • Gas
  • Phase equilibration
  • 5
  • POMD
  • 4
  • 1
  • Mole fraction - 4 ; Liquid - 4
  • Temperature, K; Liquid - 4
  • Pressure, kPa; Liquid - 4
  • Liquid - 4
  • Gas
  • Phase equilibration
  • 20
  • POMD
  • 3
  • 1
  • Mole fraction - 3 ; Liquid - 3
  • Temperature, K; Liquid - 3
  • Pressure, kPa; Liquid - 3
  • Liquid - 3
  • Gas
  • Phase equilibration
  • 24
  • POMD
  • 2
  • 1
  • Mole fraction - 2 ; Liquid - 2
  • Temperature, K; Liquid - 2
  • Pressure, kPa; Liquid - 2
  • Liquid - 2
  • Gas
  • Phase equilibration
  • 30