Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor Phase PTx Measurements of Binary Blends of 2,3,3,3-Tetrafluoroprop-1-ene + Isobutane and trans-1,3,3,3-Tetrafluoroprop-1-ene + Isobutane

Brown, J. Steven, Coccia, Gianluca, Tomassetti, Sebastiano, Pierantozzi, Mariano, Nicola, Giovanni Di
J. Chem. Eng. Data 2017, 62, 10, 3577-3584
ABSTRACT
The paper presents ninety-six PvTx vapor phase data for binary blends of 2,3,3,3- tetrafluoroprop-1-ene (R1234yf) and isobutane (R600a) and one hundred-two PvTx vapor phase data for binary blends of trans-1,3,3,3-tetrafluoroprop-1-ene (R1234ze(E)) and R600a. The R1234yf/R600a blends were measured for five isochores (0.080, 0.094, 0.128, 0.166, 0.170) m3*kg-1 for (303 less than T less than 383) K for six R600a mole fractions (0.234, 0.400, 0.472, 0.606, 0.772, 0.850) mol*mol-1. The R1234ze(E)/R600a blends were measured for four isochores (0.085, 0.090, 0.101, 0.106) m3*kg-1 for (303 less than T less than 383) K for six R600a mole fractions (0.290, 0.428, 0.516, 0.612, 0.685, 0.755) mol*mol-1. The data were fitted with a Fundamental Helmoltz Equation of State (EoS), a Peng-Robinson EoS, and a truncated Virial EoS.
Compounds
# Formula Name
1 C4H10 2-methylpropane
2 C3H2F4 2,3,3,3-tetrafluoro-1-propene
3 C3H2F4 trans-1,3,3,3-tetrafluoropropene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Specific volume, m3/kg ; Gas
  • Mole fraction - 1; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • ISOCHOR
  • 96
  • POMD
  • 1
  • 3
  • Specific volume, m3/kg ; Gas
  • Mole fraction - 1; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • ISOCHOR
  • 102