The solubility of carbonyl sulfide (COS) in two low vapor pressure organic solvents, namely, sulfolane (SFL) and gamma-butyrolactone (GBL) was measured by experimental trial. Gas solubility determined by using isochoric saturation method under static situation at temperatures from (303.15 to 353.15) K and pressure from vapor pressure of solvent up to about 1.2 MPa. The absorption data were correlated by using Peng-Robinson-Stryjek-Vera (PRSV) cubic equation of state as o-o approach, and Krichevsky-Ilinskaya (KI) model with combination of the PRSV EoS as a-o one. Using the solubility data, Henry s law constant, Gibbs free energy, enthalpy, entropy and gas molar volume at infinitely diluted solutions were calculated and interpreted.
Compounds
#
Formula
Name
1
COS
carbonyl sulfide
2
C4H6O2
.gamma.-butyrolactone
3
C4H8O2S
sulfolane
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.