Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

pvT Properties of 2,3,3,3-Tetrafluoroprop-1-ene (HFO-1234yf) in the Gaseous Phase

Hu, Peng, Cai, Xu-Dong, Chen, Long-Xiang, Xu, Hang, Zhao, Gang
J. Chem. Eng. Data 2017, 62, 10, 3353-3359
ABSTRACT
2,3,3,3-tetrafluoroprop-1-ene (HFO-1234yf) is considered as the promising alternative low-GWP refrigerant to replace HFC-134a. In this study, the gaseous pvT properties of HFO-1234yf were measured at temperatures from 252 K to 345 K and pressures up to 1.91 MPa using a single-sinker densimeter. The density range is from 3.732 kg/m3 to 112.152 kg/m3. The standard uncertainties of the experimental data are estimated as 6 mK and 0.7 kPa for the temperature and pressure, respectively. The relative uncertainty in density is (0.014 to 0.034) % in this study. The average absolute deviation and relative deviation of density from reported equation of state are 0.023 kg/m3 and 0.156 %, respectively. A virial equation of state was developed for HFO-1234yf. The calculated results show good agreement with the experimental data.
Compounds
# Formula Name
1 C3H2F4 2,3,3,3-tetrafluoro-1-propene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • Buoyancy - hydrostatic balance with magnetic suspension - one sinker
  • 83