ABSTRACT

The density and viscosity of the cyclopropyl methyl ketone (CPMK) + 2-acetylbutyrolactone (ABL) and CPMK + 5-chloro-2-pentanone (CPE) binary mixtures were measured at the temperature range of 303.15 K to 333.15 K at atmospheric pressure (about 101.325 +- 0.3 kPa). The excess molar volume and viscosity deviation were calculated based on the experimental data of density and viscosity, and they could be accurately described by the Redlich-Kister equation. In addition, the vapor-liquid equilibrium (VLE) data for the CPMK-ABL binary system were measured at atmospheric pressure. It was shown that there is no azeotrope in this binary mixture. The VLE data were correlated with NRTL, Wilson and UNIQUAC models and the interaction parameters obtained were reported. The prediction accuracies of these models were about the same.

Compounds

#	Formula	Name
1	C5H8O	1-cyclopropyl ethanone
2	C6H8O3	2-acetylbutyrolactone
3	C5H9ClO	1-chloro-4-pentanone

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	12
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	4
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	4
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	15
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	4
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	4
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	13
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	4
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	4
POMD	1 2	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	44
POMD	1 2	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	44
POMD	1 2	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	16
POMD	1 2	Mole fraction - 1 ; Gas	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Gas Liquid	Chromatography	16
POMD	1 3	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	40
POMD	1 3	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	40

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density, Viscosity, and Vapor-Liquid Equilibrium Data for the Binary Mixture at Atmosphere Pressure: Cyclopropyl Methyl Ketone + 2-Acetylbutyrolactone, Cyclopropyl Methyl Ketone + 5-Chloro-2-pentanone

Wang, Xiaoda, Gao, Yuan, Yang, Jinbei, Huang, Zhixian, Qiu, Ting

ABSTRACT