Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurements of (Solid + Liquid) Phase Equilibria in the Quaternary System NaBr + KBr + SrBr2 + H2O and Two Subsystems NaBr + SrBr2 + H2O and KBr + SrBr2 + H2O at T = 323 K

Cui, Rui-Zhi, Nie, Guo-Liang, Sang, Shi-Hua, Yang, Lei, Wang, Zhou-Chi
J. Chem. Eng. Data 2017, 62, 10, 3187-3192
ABSTRACT
The (solid + liquid) phase equilibria of the NaBr + KBr + SrBr2 + H2O quaternary system and two subsystems (NaBr + SrBr2 + H2O and KBr + SrBr2 + H2O) were studied at T = 323 K using isothermal dissolution method. With the solubility values of each system, the stable phase diagrams of these systems were drawn. It shows that there is neither solid solution nor double salt in diagrams. Three systems are all of the hydrate type I, and only one invariant point is found in the phase diagrams of three systems.
Compounds
# Formula Name
1 BrNa sodium bromide
2 BrK potassium bromide
3 Br2Sr strontium bromide (SrBr2)
4 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 3
  • 4
  • Mass fraction - 3 ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Titration method
  • 12
  • POMD
  • 2
  • 3
  • 4
  • Mass fraction - 3 ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Titration method
  • 5
  • POMD
  • 1
  • 2
  • 4
  • Mass fraction - 2 ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Titration method
  • 1
  • POMD
  • 1
  • 2
  • 4
  • Mass fraction - 2 ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Titration method
  • 1
  • POMD
  • 1
  • 3
  • 4
  • Mass fraction - 3 ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Titration method
  • 11
  • POMD
  • 1
  • 3
  • 4
  • Mass fraction - 3 ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 2
  • Titration method
  • 7
  • POMD
  • 2
  • 4
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Titration method
  • 1
  • POMD
  • 3
  • 4
  • Mass fraction - 3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Titration method
  • 1
  • POMD
  • 3
  • 4
  • Mass fraction - 3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 2
  • Titration method
  • 1
  • POMD
  • 1
  • 4
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Titration method
  • 1