Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Gaseous PVT Property Measurements of cis-1,3,3,3-Tetrafluoropropene

Sakoda, N.[Naoya], Shiheng, J.[Jiang], Kohno, M.[Masamichi], Koyama, S.[Shigeru], Higashi, Y.[Yukihiro], Takata, Y.[Yasuyuki]
J. Chem. Eng. Data 2017, 62, 7, 2178-2182
ABSTRACT
PVT properties in the vapor phase of cis-1,3,3,3-tetrafluoropropene (R1234ze(Z)) were measured by a multiple expansion method in the temperature range from 353 to 413 K and at pressures up to 2.7 MPa. Thirty data along four isotherms are obtained in the temperatures between 353 and 413 K. The vapor pressures at the temperatures were also measured by adding a sample of R1234ze(Z) to a sample cell at the vapor liquid equilibrium conditions. The uncertainties in temperature and pressure measurements are estimated to be within 6 mK and 0.3 kPa, respectively. The expanded uncertainty in density measurement is estimated within no greater than 0.12% (k = 2). The obtained PVT properties and vapor pressures are compared with the existing equation of state.
Compounds
# Formula Name
1 He helium
2 N2 nitrogen
3 C3H2F4 (Z)-1,3,3,3-tetrafluoro-1-propene
4 C2H2F4 1,1,1,2-tetrafluoroethane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Amount density, mol/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • ISOCHOR
  • 24
  • POMD
  • 2
  • Amount density, mol/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • ISOCHOR
  • 16
  • POMD
  • 3
  • Amount density, mol/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • ISOCHOR
  • 30
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 4
  • POMD
  • 4
  • Amount density, mol/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • ISOCHOR
  • 17