Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

The Critical Temperatures of a Number of (i) (Chloroalkane (C3 C4) + Hydrocarbon (C6 C7)) Binary Mixtures and (ii) (Aromatic Halocarbon (Chlorobenzene, Fluorobenzene, 1,2-Dichlorobenzene, or 1,3-Dichlorobenzene) + Alkane (C8)) Binary Mixtures

Young, C. L.[Colin L.], Tran, C. A.[Cam A.], Morton, D. W.[David W.]
J. Chem. Eng. Data 2017, 62, 9, 2953-2958
ABSTRACT
In the last 30 years, little experimental work has been reported on the critical properties of (halogenated hydrocarbon + hydrocarbon) mixtures. Furthermore, the overall amount of reported critical property data for these types of mixtures is quite small. This work aims to extended the existing data set and presents data on the critical temperatures of (i) 14 different chloroalkane (C3 C4) + hydrocarbon mixtures (C6 C7) as a function of mole fraction and (ii) 10 different aromatic halocarbons (chlorobenzene, fluorobenzene, 1,2-dichlorbenzene, or 1,3-dichlorobenzene) + alkanes (C8) as a function of mole fraction. All of the (gas + liquid) critical lines were continuous. Therefore, all mixtures displayed either Type I or Type II behavior.
Compounds
# Formula Name
1 C6H6 benzene
2 C6H12 cyclohexane
3 C8H16 cyclooctane
4 C4H9Cl 1-chlorobutane
5 C6H5Cl chlorobenzene
6 C6H4Cl2 1,2-dichlorobenzene
7 C6H4Cl2 1,3-dichlorobenzene
8 C3H6Cl2 1,2-dichloropropane
9 C3H6Cl2 1,3-dichloropropane
10 C6H14 2,2-dimethylbutane
11 C6H5F fluorobenzene
12 C6H14 hexane
13 C7H16 heptane
14 C8H18 octane
15 C8H18 2,2,4-trimethylpentane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Critical temperature, K ; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 1
  • POMD
  • 6
  • Critical temperature, K ; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 1
  • POMD
  • 10
  • Critical temperature, K ; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 1
  • POMD
  • 11
  • Critical temperature, K ; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 1
  • POMD
  • 12
  • Critical temperature, K ; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 1
  • POMD
  • 13
  • Critical temperature, K ; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 1
  • POMD
  • 14
  • Critical temperature, K ; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 1
  • POMD
  • 15
  • Critical temperature, K ; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 1
  • POMD
  • 1
  • 8
  • Critical temperature, K ; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 8
  • POMD
  • 8
  • 2
  • Critical temperature, K ; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 9
  • POMD
  • 10
  • 8
  • Critical temperature, K ; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 8
  • POMD
  • 8
  • 12
  • Critical temperature, K ; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 8
  • POMD
  • 8
  • 13
  • Critical temperature, K ; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 9
  • POMD
  • 1
  • 9
  • Critical temperature, K ; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 9
  • POMD
  • 2
  • 9
  • Critical temperature, K ; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 6
  • POMD
  • 10
  • 9
  • Critical temperature, K ; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 8
  • POMD
  • 12
  • 9
  • Critical temperature, K ; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 8
  • POMD
  • 9
  • 13
  • Critical temperature, K ; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 9
  • POMD
  • 1
  • 4
  • Critical temperature, K ; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 7
  • POMD
  • 4
  • 2
  • Critical temperature, K ; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 9
  • POMD
  • 4
  • 15
  • Critical temperature, K ; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 8
  • POMD
  • 4
  • 12
  • Critical temperature, K ; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 8
  • POMD
  • 11
  • 15
  • Critical temperature, K ; Liquid
  • Mole fraction - 15; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 9
  • POMD
  • 5
  • 15
  • Critical temperature, K ; Liquid
  • Mole fraction - 15; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 7
  • POMD
  • 6
  • 15
  • Critical temperature, K ; Liquid
  • Mole fraction - 15; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 8
  • POMD
  • 15
  • 7
  • Critical temperature, K ; Liquid
  • Mole fraction - 15; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 8
  • POMD
  • 3
  • 11
  • Critical temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 7
  • POMD
  • 5
  • 3
  • Critical temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 7
  • POMD
  • 6
  • 3
  • Critical temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 7
  • POMD
  • 3
  • 7
  • Critical temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 6
  • POMD
  • 6
  • 14
  • Critical temperature, K ; Liquid
  • Mole fraction - 14; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 9
  • POMD
  • 14
  • 7
  • Critical temperature, K ; Liquid
  • Mole fraction - 14; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 7