2 0 2017 fer zan 0 journal Original Ferreira-Pinto, L.[Leandro] Zanette, A.[Andreia] Voll, F. A. P.[Fernando Augusto Pedersen] Cabral, V. F.[Vladimir Ferreira] Castier, M.[Marcelo] Cardozo-Filho, L.[Lucio] J. Chem. Eng. Data 2017 2020-09-29 Vapor Liquid Equilibrium of Carbon Dioxide + Ethyl Acetate + Oleic Acid Mixtures at High Pressures In this work, experimental data for the phase transition of ternary systems {CO2 (1) + ethyl acetate (2) + oleic acid (3)} at global CO2 mole fraction values from 0.5 to 1, at the temperatures of 308, 318, 328, and 338 K are reported. A variable volume cell was used, following the static synthetic method for pressures of up to 21 MPa. The ethyl acetate/oleic acid molar ratio was set to 3:1 [0.750 ethyl acetate + 0.250 oleic acid], 9:1 [0.900 ethyl acetate + 0.100 oleic acid], and 199:1 [0.995 ethyl acetate + 0.005 oleic acid]. In all of these ternary systems, bubble point and dew points were observed. Oleic Acid Ethyl Acetate, Vapor-liquid Equilibrium, High Pressure, Peng-Robinson Equation of State 10.1021/acs.jced.7b00163 9 62 2855-2860 1 InChI=1S/C18H34O2/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20/h9-10H,2-8,11-17H2,1H3,(H,19,20)/b10-9- ZQPPMHVWECSIRJ-KTKRTIGZSA-N (Z)-9-octadecenoic acid .DELTA.9-cis-octadecenoic acid .DELTA.9-cis-oleic acid 9-cis-octadecenoic acid 9-octadecenoic acid, (Z)- cis-.DELTA.9-octadecenoic acid cis-9-octadecenoic acid cis-oleic acid emersol 205 extraolein 90 industrene 105 lunac O-CA oleic acid oleine 7503 pamolyn 100 priolene 6907 vopcolene 27 wecoline OO C18H34O2 1 Commercial source 1 99 2 Stated by supplier 2 InChI=1S/C4H8O2/c1-3-6-4(2)5/h3H2,1-2H3 XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate ethyl ethanoate C4H8O2 1 Commercial source 1 99.5 3 Stated by supplier 3 InChI=1S/CO2/c2-1-3 CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide CO2 1 Commercial source 1 99.9 3 Stated by supplier 1 3 1 2 1 1 1 Principal objective of the work EP EP 7/10/2017 1 Vapor or sublimation pressure, kPa Closed cell (Static) method Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid Gas 1 Temperature, K Liquid 2 Mole fraction 3 Liquid 3 Mole fraction 2 Liquid 1 308 3 2 0.5 3 3 0.375 3 1 3440 3 1 50 1 308 3 2 0.6 3 3 0.3 3 1 4000 3 1 70 1 308 3 2 0.7 3 3 0.22 3 1 5060 3 1 70 1 308 3 2 0.8 3 3 0.15 3 1 5200 3 1 120 1 318 3 2 0.5 3 3 0.375 3 1 3240 3 1 40 1 318 3 2 0.6 3 3 0.3 3 1 4060 3 1 60 1 318 3 2 0.7 3 3 0.22 3 1 4980 3 1 70 1 318 3 2 0.8 3 3 0.15 3 1 6240 3 1 140 1 328 3 2 0.5 3 3 0.375 3 1 3810 3 1 90 1 328 3 2 0.6 3 3 0.3 3 1 5090 3 1 110 1 328 3 2 0.7 3 3 0.22 3 1 6170 3 1 140 1 328 3 2 0.8 3 3 0.15 3 1 7490 3 1 160 1 338 3 2 0.5 3 3 0.375 3 1 4500 3 1 90 1 338 3 2 0.6 3 3 0.3 3 1 5850 3 1 100 1 338 3 2 0.7 3 3 0.22 3 1 7450 3 1 140 1 338 3 2 0.8 3 3 0.15 3 1 9340 3 1 190 1 308 3 2 0.5 3 3 0.45 3 1 3340 3 1 70 1 308 3 2 0.6 3 3 0.36 3 1 4450 3 1 70 1 308 3 2 0.7 3 3 0.27 3 1 4620 3 1 90 1 308 3 2 0.8 3 3 0.18 3 1 5550 3 1 140 1 308 3 2 0.85 3 3 0.13 3 1 6140 3 1 130 1 308 3 2 0.9 3 3 0.09 2 1 6480 3 1 3360 1 308 3 2 0.95 3 3 0.045 2 1 13370 4 1 360 1 318 3 2 0.5 3 3 0.45 3 1 4020 3 1 70 1 318 3 2 0.6 3 3 0.36 3 1 4520 3 1 80 1 318 3 2 0.7 3 3 0.27 3 1 5590 3 1 110 1 318 3 2 0.8 3 3 0.18 3 1 6810 3 1 130 1 318 3 2 0.85 3 3 0.13 3 1 7270 3 1 140 1 318 3 2 0.9 3 3 0.09 2 1 8830 3 1 2670 1 318 3 2 0.95 3 3 0.045 2 1 15660 4 1 360 1 328 3 2 0.5 3 3 0.45 3 1 4250 3 1 80 1 328 3 2 0.6 3 3 0.36 3 1 5310 3 1 110 1 328 3 2 0.7 3 3 0.27 3 1 6580 3 1 110 1 328 3 2 0.8 3 3 0.18 3 1 7870 3 1 130 1 328 3 2 0.85 3 3 0.13 3 1 8610 3 1 150 1 338 3 2 0.5 3 3 0.45 3 1 4930 3 1 70 1 338 3 2 0.6 3 3 0.36 3 1 6280 3 1 120 1 338 3 2 0.7 3 3 0.27 3 1 7620 3 1 120 1 338 3 2 0.8 3 3 0.18 3 1 9190 3 1 130 1 308 3 2 0.5 3 3 0.498 3 1 3450 3 1 60 1 308 3 2 0.6 3 3 0.398 3 1 4030 3 1 110 1 308 3 2 0.7 3 3 0.299 3 1 4700 3 1 90 1 308 3 2 0.8 3 3 0.199 3 1 5880 3 1 90 1 318 3 2 0.5 3 3 0.498 3 1 3810 3 1 60 1 318 3 2 0.6 3 3 0.398 3 1 4870 3 1 90 1 318 3 2 0.7 3 3 0.299 3 1 5590 3 1 100 1 318 3 2 0.8 3 3 0.199 3 1 6580 3 1 100 1 328 3 2 0.5 3 3 0.498 3 1 4430 3 1 70 1 328 3 2 0.6 3 3 0.398 3 1 5340 3 1 70 1 328 3 2 0.7 3 3 0.299 3 1 6470 3 1 100 1 328 3 2 0.8 3 3 0.199 3 1 7530 3 1 120 1 338 3 2 0.5 3 3 0.498 3 1 4960 3 1 60 1 338 3 2 0.6 3 3 0.398 3 1 6120 3 1 100 1 338 3 2 0.7 3 3 0.299 3 1 7410 3 1 100 1 338 3 2 0.8 3 3 0.199 3 1 8670 3 1 140 2 3 1 2 1 1 1 Principal objective of the work EP EP 7/10/2017 1 Vapor or sublimation pressure, kPa Closed cell (Static) method Gas Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Gas Liquid 1 Temperature, K Gas 2 Mole fraction 3 Gas 3 Mole fraction 2 Gas 1 308 3 2 0.9 3 3 0.075 2 1 12600 4 1 600 1 318 3 2 0.9 3 3 0.075 2 1 13550 4 1 620 1 328 3 2 0.9 3 3 0.075 2 1 15250 4 1 650 1 338 3 2 0.9 3 3 0.075 2 1 16920 4 1 590 1 328 3 2 0.9 3 3 0.09 2 1 11330 4 1 700 1 328 3 2 0.95 3 3 0.045 2 1 18280 4 1 1880 1 338 3 2 0.85 3 3 0.135 3 1 10140 4 1 220 1 338 3 2 0.9 3 3 0.09 2 1 13750 4 1 740 1 338 3 2 0.95 3 3 0.045 2 1 21350 4 1 2280 1 308 3 2 0.85 3 3 0.149 3 1 5830 3 1 990 1 308 3 2 0.9 3 3 0.1 3 1 6560 3 1 670 1 308 3 2 0.95 3 3 0.05 2 1 7000 3 1 2040 1 318 3 2 0.85 3 3 0.149 3 1 7010 3 1 1010 1 318 3 2 0.9 3 3 0.1 3 1 7620 3 1 640 1 318 3 2 0.95 3 3 0.05 2 1 8200 3 1 2030 1 328 3 2 0.85 3 3 0.149 3 1 8130 3 1 970 1 328 3 2 0.9 3 3 0.1 3 1 9030 3 1 600 1 328 3 2 0.95 3 3 0.05 2 1 9470 3 1 2030 1 338 3 2 0.85 3 3 0.149 3 1 9420 3 1 230 1 338 3 2 0.9 3 3 0.1 3 1 10150 4 1 890 1 338 3 2 0.95 3 3 0.05 2 1 10680 4 1 2450 3 3 1 2 1 Principal objective of the work EP EP 7/10/2017 1 Vapor or sublimation pressure, kPa Closed cell (Static) method Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid Gas 1 Temperature, K Liquid 2 Mole fraction 3 Liquid 1 308 3 2 0.5 1 1 3450 3 1 60 1 308 3 2 0.6 1 1 4030 3 1 100 1 308 3 2 0.7 1 1 4700 3 1 80 1 308 3 2 0.8 1 1 5880 3 1 90 1 318 3 2 0.5 1 1 3810 3 1 60 1 318 3 2 0.6 1 1 4870 3 1 90 1 318 3 2 0.7 1 1 5590 3 1 100 1 318 3 2 0.8 1 1 6580 3 1 100 1 328 3 2 0.5 1 1 4430 3 1 70 1 328 3 2 0.6 1 1 5340 3 1 70 1 328 3 2 0.7 1 1 6470 3 1 100 1 328 3 2 0.8 1 1 7530 3 1 120 1 338 3 2 0.5 1 1 4960 3 1 60 1 338 3 2 0.6 1 1 6120 3 1 100 1 338 3 2 0.7 1 1 7410 3 1 100 1 338 3 2 0.8 1 1 8670 3 1 130 4 3 1 2 1 Principal objective of the work EP EP 7/10/2017 1 Vapor or sublimation pressure, kPa Closed cell (Static) method Gas Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Gas Liquid 1 Temperature, K Gas 2 Mole fraction 3 Gas 1 308 3 2 0.85 2 1 5830 3 1 120 1 308 3 2 0.9 1 1 6560 3 1 120 1 308 3 2 0.95 2 1 7000 3 1 120 1 318 3 2 0.85 2 1 7010 3 1 120 1 318 3 2 0.9 1 1 7620 3 1 130 1 318 3 2 0.95 2 1 8200 3 1 130 1 328 3 2 0.85 2 1 8130 3 1 130 1 328 3 2 0.9 1 1 9030 3 1 140 1 328 3 2 0.95 2 1 9470 3 1 130 1 338 3 2 0.85 2 1 9420 3 1 140 1 338 3 2 0.9 1 1 10150 4 1 110 1 338 3 2 0.95 2 1 10680 4 1 130