Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement of p.rho.T Properties of 1,1,1,2,2,4,5,5,5-Nonafluoro-4-(trifluoromethyl)-3-pentanone in the Near-Critical and Supercritical Regions

Tanaka, K.[Katsuyuki]
J. Chem. Eng. Data 2016, 61, 11, 3958-3961
ABSTRACT
In this work, measurements of pT (pressure density temperature) properties of 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone in the near-critical and supercritical regions were carried out. This novel fluid has potential for use in next generation organic Rankine cycle systems because its GWP (global warming potential) is 1. However, there is insufficient data available especially near the critical point. In this work, 155 pT data points of 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone along 21 isochores were obtained for densities between 107 and 1526 kg*m 3, for temperatures ranging from 333.5 to 523.5 K, and at pressures up to 10 MPa. The experimental uncertainties in the measurements of temperatures, pressures, and densities were estimated to be 0.028 K, 4 kPa, and 0.5%, respectively. For densities above 200 kg*m 3, the uncertainty is 0.4%.
Compounds
# Formula Name
1 C6F12O dodecafluoro-2-methylpentan-3-one
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • ISOCHOR
  • 155