ABSTRACT

The solubility of e-CL-20 was assessed in 12 organic solvents by the equilibrium method at temperatures ranging from 278.15 to 318.15 K and 0.1 MPa. The order of the solubility of e-CL-20 was ethyl acetate greater than butyl acetate greater than triethyl-orthoformate greater than methanol greater than ethanol greater than propanol greater than 1-butanol greater than isopropyl alcohol greater than m-xylene greater than chloroform greater than toluene greater than cyclohexane. The modified Apelblat equation was used to correlate the experimental solubility values at these temperatures in these solvents and the results showed good agreement with the experimental values.

Compounds

#	Formula	Name
1	C6H6N12O12	2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane
2	CH4O	methanol
3	C2H6O	ethanol
4	C3H8O	propan-1-ol
5	C3H8O	propan-2-ol
6	C4H8O2	ethyl acetate
7	C7H8	toluene
8	CHCl3	trichloromethane
9	C7H16O3	ethyl orthomethanoate
10	C8H10	1,3-dimethylbenzene
11	C4H10O	butan-1-ol
12	C6H12O2	butyl ethanoate
13	C6H12	cyclohexane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9
POMD	3 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9
POMD	4 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9
POMD	5 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9
POMD	11 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9
POMD	8 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9
POMD	10 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9
POMD	7 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9
POMD	12 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9
POMD	6 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9
POMD	13 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	8
POMD	9 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement and Correlation of the Solubility of e-CL-20 in 12 Organic Solvents at Temperatures Ranging from 278.15 to 318.15 K

Lv, P.[Penghao], Wang, H.[HuiYun], Tong, Y.[Yao], Dang, L.[Leping], Sun, C.[Chenghui], Pang, S.-P.[Si-Ping]

ABSTRACT