Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Activity Coefficients of RbF in the RbF + RbBr + H2O and RbF + RbNO3 + H2O Ternary Systems Using the Potentiometric Method at 298.2 K

Huang, X.[Xiaoting], Li, S.[Shu'ni], Zhai, Q.[Quanguo], Jiang, Y.[Yucheng], Hu, M.[Mancheng]
J. Chem. Eng. Data 2016, 61, 10, 3481-3487
ABSTRACT
Thermodynamic properties of the RbF + RbBr + H2O and RbF + RbNO3 + H2O systems were determined by the potentiometric method at the total ionic strengths ranging from 0.0017 to 0.7005 mol*kg 1 for different ionic strength fractions yB of RbBr/RbNO3 with yB = 0.00, 0.30, 0.60, and 0.90, at 298.2 K. Combining the Nernst equation and Pitzer equation, the mean ionic activity coefficients of RbF and RbBr/RbNO3, the osmotic coefficients, and the excess Gibbs energies of the studied systems were calculated.
Compounds
# Formula Name
1 H2O water
2 FRb rubidium fluoride (RbF)
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Mean ionic activity coefficient - 2 ; Liquid
  • Molality, mol/kg - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Calculated from EMF cell potential
  • 32