ABSTRACT

Vapor liquid equilibrium (VLE) at P = 50 and 100 kPa data for binary systems (Z,E-2-methyl-2-butenenitrile + R,S-4-vinyl-1-cyclohexene) and system (Z,E-2-methyl-2-butenenitrile + Z,E-3-pentenenitrile) was determined. All experimental VLE data were tested by the point test and were proven to be thermodynamically consistent. Activity coefficient correlation models (Wilson and NRTL models) were used to calculate all VLE experimental data. The model parameters were obtained by correlating the experimental data. The VLE data calculated from parameters were consistent with the experimental values.

Compounds

#	Formula	Name
1	C5H7N	2-methyl-2-butenenitrile
2	C8H12	4-ethenylcyclohexene
3	C5H7N	3-pentenenitrile

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	2
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	2
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	2
POMD	2 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid Pressure, kPa; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	22
POMD	2 1	Mole fraction - 1 ; Gas	Mole fraction - 1; Liquid Pressure, kPa; Liquid	Gas Liquid	Chromatography	22
POMD	1 3	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid Pressure, kPa; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	22
POMD	1 3	Mole fraction - 1 ; Gas	Mole fraction - 1; Liquid Pressure, kPa; Liquid	Gas Liquid	Chromatography	22

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Isobaric Vapor Liquid Equilibria for Binary Mixtures of Z,E-2-Methyl-2-butenenitrile, R,S-4-Vinyl-1-cyclohexene, and Z,E-3-Pentenenitrile

He, Z.[Zhijian], Song, H.[Hang], Wang, Z.[Zhixia], Cao, Y.[Yu]

ABSTRACT