Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Experimental Study on the Saturated Liquid Density and Bubble Point Pressure for R1234ze(E) + R290

Zhang, H.[Haiyang], Zhong, Q.[Quan], Gong, M.[Maoqiong], Li, H.[Huiya], Dong, X.[Xueqiang], Shen, J.[Jun], Wu, J.[Jianfeng]
J. Chem. Eng. Data 2016, 61, 9, 3241-3249
ABSTRACT
Saturated liquid densities and bubble point pressures of trans-1,3,3,3-tetrafluoropropene (R1234ze(E)) + propane (R290) binary mixture were measured at temperatures from (253.141 to 293.284) K and mole fractions of R1234ze(E) from (0.1746 to 0.8803) using a compact single-sinker densimeter. The standard uncertainties were estimated to be less than 5 mK for temperature, 600 Pa for pressure, 0.003 for mole fraction, and 0.01% for density. The experimental saturated liquid densities were reproduced by the VDNS and our modified Rackett density equations, while the experimental bubble point pressures were represented with the Patel Teja (PT) equation of state. Good agreement between values of calculation and experiment were found for both saturated liquid densities and bubble point pressures. In addition, saturated vapor and liquid densities of azeotropy point at temperatures T = (258.150, 263.150, 273.150 and 283.150) K were determined.
Compounds
# Formula Name
1 C3H2F4 trans-1,3,3,3-tetrafluoropropene
2 C3H8 propane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Buoyancy - hydrostatic balance with magnetic suspension - one sinker
  • 35
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 35