Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Determining the Solubility of Organic Compounds in Supercritical Carbon Dioxide Using Supercritical Fluid Chromatography Directly Interfaced to Supercritical Fluid Solubility Apparatus

Li, B.[Ben], Guo, W.[Wei], Song, W.[Wei], Ramsey, E. D.[Edward D.]
J. Chem. Eng. Data 2016, 61, 6, 2128-2134
ABSTRACT
The solubilities of benzoin and 3,3',4,4'-benzophenonetetracarboxylic dianhydride in supercritical fluid carbon dioxide have been measured using static supercritical fluid solubility apparatus directly interfaced to supercritical fluid chromatography (SFC). The method involves increasing the pressure of supercritical fluid carbon dioxide in controlled steps to produce a series of saturated sample solutions that are sequentially analyzed by online SFC. The system requires minimal manual sample manipulation stages and facilitates a self-validation check procedure. Solubility data for benzoin was determined at 308 and 318 K through the pressure range of 12 24 MPa using 2 MPa steps. Solubility data for 3,3',4,4'-benzophenonetetracarboxylic dianhydride was determined at 328 and 343 K through the pressure range 15 27.5 MPa using 2.5 MPa steps. The Mendez-Santiago and Teja model has been successfully applied to correlate all sets of experimental solubility data.
Compounds
# Formula Name
1 C14H12O2 .alpha.-hydroxy-.alpha.-phenylacetophenone
2 C17H6O7 3,3',4,4'-benzophenonetetracarboxylic dianhydride
3 CO2 carbon dioxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • Liquid
  • Chromatography
  • 14
  • POMD
  • 3
  • 2
  • Mole fraction - 2 ; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • Liquid
  • Chromatography
  • 12