Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Liquid Liquid Equilibria of Binary and Ternary Systems Methanol/Water + n-Hexane, + n-Octane, + n-Dodecane, and + n-Hexadecane in the Temperature Range between T = 283.15 K and T = 333.15 K

Lindemann, C.[Cecile], Duchet-Suchaux, P.[Pierre], Razzouk, A.[Antonio], Mokbel, I.[Ilham], Jose, J.[Jacques]
J. Chem. Eng. Data 2016, 61, 7, 2412-2418
ABSTRACT
Original very low solubility data for binary (methanol + dodecane) and ternary systems (methanol/water + hexane, or octane, or dodecane, or hexadecane) under atmospheric pressure at three temperatures between 283.15 and 333.15 K are reported. The experimental values were compared with literature data when available. Two models (NRTL and UNIQUAC) were used to correlate and predict the experimental data.
Compounds
# Formula Name
1 CH4O methanol
2 C6H14 hexane
3 C8H18 octane
4 C12H26 dodecane
5 C16H34 hexadecane
6 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 6
  • Mole fraction - 6 ; Liquid mixture 2
  • Mole fraction - 2 ; Liquid mixture 1
  • Mole fraction - 1 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • Chromatography
  • Chromatography
  • 9
  • POMD
  • 1
  • 3
  • 6
  • Mole fraction - 6 ; Liquid mixture 2
  • Mole fraction - 3 ; Liquid mixture 1
  • Mole fraction - 1 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • Chromatography
  • Chromatography
  • 12
  • POMD
  • 1
  • 4
  • 6
  • Mole fraction - 6 ; Liquid mixture 2
  • Mole fraction - 4 ; Liquid mixture 1
  • Mole fraction - 1 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • Chromatography
  • Chromatography
  • 12
  • POMD
  • 1
  • 5
  • 6
  • Mole fraction - 1 ; Liquid mixture 1
  • Mole fraction - 6 ; Liquid mixture 2
  • Mole fraction - 1 ; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Mole fraction - 5; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • Chromatography
  • Chromatography
  • 3
  • POMD
  • 1
  • 4
  • Mole fraction - 1 ; Liquid mixture 2
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • 3