ABSTRACT

The viscosities ? of some monosaccharides, their methyl- and deoxy- derivatives, disaccharides, and trisaccharides have been measured in (0.25, 0.5, 1.0, and 1.25) mol*kg 1 aqueous solutions of potassium phosphate (KH2PO4) and (0.5, 1.0, 1.5, and 2.0) mol*kg 1 aqueous solutions of sodium phosphate (NaH2PO4) and ammonium phosphate (NH4H2PO4) monobasic salts, and potassium phosphate (K3PO4) tribasic salt over the temperature range (288.15 to 318.15) K and at atmospheric pressure, P = 0.1 MPa. The viscosity data have been utilized to calculate the Jones Dole viscosity B-coefficients and their corresponding coefficients of transfer, tB. The tB values were found to be positive and their magnitudes vary depending on the nature of solutes and cosolutes. The dB/dT coefficients and pair AB and triplet ABB interaction coefficients have also been calculated and discussed in terms of solute solvent/cosolute interactions. The results have been compared in phosphate-based salts on the basis of the nature of the cation and anion.

Compounds

#	Formula	Name
1	C5H10O5	D-xylose
2	C5H10O5	D-ribose
3	C6H12O6	D-fructose
4	C6H12O6	D-glucose
5	C6H12O6	D-mannose
6	C5H10O4	2-deoxy-D-erythropentose
7	C6H12O5	2-deoxy-D-glucose
8	C6H12O5	6-deoxy-.alpha.-L-mannopyranose
9	C7H14O6	.alpha.-methyl mannopyranoside
10	C7H14O6	methyl-.alpha.-D-glucopyranoside
11	C12H22O11	D-sucrose
12	C12H22O11	D-cellobiose
13	C12H22O11	4-O-.beta.-D-galactopyranosyl-D-glucose
14	C12H22O11	D-maltose
15	C18H32O16	O-.alpha.-glucopyranosyl-(1,3)-O-.beta.-D- fructofuranosyl-(2,1)-.alpha.-D-glucopyranoside
16	C18H32O16	D-raffinose
17	H2KO4P	monopotassium phosphate
18	H2NaO4P	sodium dihydrogen phosphate
19	H6NO4P	ammonium dihydrogen phosphate
20	K3O4P	tripotassium phosphate
21	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	4
POMD	1 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	140
POMD	2 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	120
POMD	3 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Amount concentration (molarity), mol/dm3 - 3; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	120
POMD	4 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	120
POMD	5 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 5; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	120
POMD	6 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 6; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	136
POMD	7 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	144
POMD	8 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 8; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	140
POMD	9 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 9; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	140
POMD	10 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 10; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	140
POMD	11 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 11; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	128
POMD	12 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 12; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	128
POMD	13 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 13; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	128
POMD	14 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 14; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	128
POMD	15 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 15; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	144
POMD	16 21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 16; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	144
POMD	1 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	2 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	3 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 3; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	4 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	5 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 5; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	6 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 6; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	80
POMD	7 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	80
POMD	8 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 8; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	80
POMD	9 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 9; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	80
POMD	10 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 10; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	11 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 11; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	12 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 12; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	13 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 13; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	14 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 14; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	15 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 15; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	80
POMD	16 18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 18; Liquid Molality, mol/kg - 16; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	80
POMD	2 19 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 19; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	108
POMD	4 19 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 19; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	5 19 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 19; Liquid Molality, mol/kg - 5; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	7 19 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 19; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	88
POMD	9 19 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 19; Liquid Molality, mol/kg - 9; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	92
POMD	11 19 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 19; Liquid Molality, mol/kg - 11; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	12 19 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 19; Liquid Molality, mol/kg - 12; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	14 19 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 19; Liquid Molality, mol/kg - 14; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	16 19 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 19; Liquid Molality, mol/kg - 16; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	2 21 20	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 20; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	120
POMD	4 21 20	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 20; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	104
POMD	10 21 20	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 20; Liquid Molality, mol/kg - 10; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	104
POMD	14 21 20	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 20; Liquid Molality, mol/kg - 14; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	112
POMD	16 21 20	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 20; Liquid Molality, mol/kg - 16; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	7 21 20	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 20; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	10 19 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 19; Liquid Molality, mol/kg - 10; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	112
POMD	21 17	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 17; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	16
POMD	1 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	24
POMD	19 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 19; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	16
POMD	21 20	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 20; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	16
POMD	2 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	24
POMD	3 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Amount concentration (molarity), mol/dm3 - 3; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	24
POMD	4 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	24
POMD	5 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 5; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	24
POMD	6 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 6; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	28
POMD	7 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	28
POMD	8 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 8; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	28
POMD	9 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 9; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	28
POMD	10 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 10; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	28
POMD	11 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 11; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	32
POMD	12 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 12; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	32
POMD	13 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 13; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	32
POMD	14 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 14; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	32
POMD	15 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 15; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	32
POMD	16 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 16; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	32
POMD	18 21	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 18; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	16

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Viscosities of Some Saccharides in Aqueous Solutions of Phosphate-Based Inorganic Salts

Banipal, P. K.[Parampaul K.], Aggarwal, N.[Neha], Banipal, T. S.[Tarlok S.]

ABSTRACT