ABSTRACT

In this work are reported densities of fourteen protic and aprotic ionic liquids in a wide temperature range, at ambient pressure and a thermodynamic modeling is performed through Mattedi-Tavares-Castier, the EOS is based on lattice gas theory. The results are quite satisfactory with deviations smaller than 0.05%. The densities of aprotic ionic liquids are presented with greater magnitudes compared to protic ILs, revealing significant differences between levels of cohesion and electrostatic contributions among the protic and aprotic ionic liquids.

Compounds

#	Formula	Name
1	C10H15F6N3O4S2	1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
2	C14H23F6N3O4S2	1-octyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide
3	C18H31F6N3O4S2	1-dodecyl-3-methyl-1H-imidazolium bis(trifluoromethylsulfonyl)amide
4	C13H23F3N2O3S	1-octyl-3-methylimidazolium trifluoromethanesulfonate
5	C11H14F6N2O4S2	1-butylpyridinium bis[(trifluoromethyl)sulfonyl]imide
6	C5H13NO3	N-methyl-2-hydroxyethylammonium acetate
7	C6H15NO3	2-hydroxy-N-methylethanaminium propionate
8	C7H17NO3	N-methyl-2-hydroxyethylammonium butanoate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	14
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	14
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	14
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	14
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	14
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	7
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	7
POMD	8	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	7

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Experimental Density of Ionic Liquids and Thermodynamic Modeling with Group Contribution Equation of State Based on the Lattice Fluid Theory

Santos, D.[Dheiver], Santos, M.[Maria], Franceschi, E.[Elton], Dariva, C.[Claudio], Barison, A.[Andersson], Mattedi, S.[Silvana]

ABSTRACT