ABSTRACT

The densities and viscosities are measured in the temperature range (293.15 to 308.15 K) and atmospheric pressure for the ternary systems [NMP][MSA] (1-methyl-2-pyrrolidinonium methanesulfonate) + LaCl3 (lanthanum chloride) + H2O, [NMP][BSA] (1-methyl-2-pyrrolidinonium benzenesulfonate) + LaCl3 + H2O, and [NMP][p-TSA] (1-methyl-2-pyrrolidinonium p-toluenesulfonate) + LaCl3 + H2O and their binary subsystems LaCl3 + H2O, [NMP][MSA] + H2O, [NMP][BSA] + H2O, and [NMP][p-TSA] + H2O. The densities and viscosities of the ternary systems are estimated using the literature equations and the corresponding properties of their binary subsystems. The comparisons of the predicted and the measured results are made.

Compounds

#	Formula	Name
1	C6H13NO4S	1-methyl-2-pyrrolidonium methylsulfonate
2	C11H15NO4S	1-methyl-2-pyrrolidinone benzenesulfonate
3	C12H17NO4S	1-methyl-2-pyrrolidinone p-toluenesulfonate
4	Cl3La	lanthanum chloride
5	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	5 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	36
POMD	5 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	36
POMD	5 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	36
POMD	5 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	36
POMD	5 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Molality, mol/kg - 3; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	36
POMD	5 3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 3; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	36
POMD	5 4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	32
POMD	5 4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	32
POMD	5 4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Molality, mol/kg - 1; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	32
POMD	5 4 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 1; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	32
POMD	5 4 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Molality, mol/kg - 2; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	32
POMD	5 4 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 2; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	32
POMD	5 4 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Molality, mol/kg - 3; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	32
POMD	5 4 3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 3; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	32

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density and Viscosity of the Ternary Systems [NMP][MSA] + LaCl3 + H2O, [NMP][BSA] + LaCl3 + H2O, and [NMP][p- TSA] + LaCl3 + H2O at Different Temperatures and Atmospheric Pressure

Ma, W.-T.[Wei-Ting], Hu, Y.-F.[Yu-Feng], Qi, J.-G.[Jian-Guang], Zhang, X.-M.[Xian-MIng], Zhao, Y.-M.[Ya-Mei]

ABSTRACT