Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Phase Equilibrium in the Ternary System NaH2PO4 + Na2SO4 + H2O at 323.15 K and 343.15 K

Xiao, Y.[Yang], Liu, W.[Wei], Han, X.[Xu]
J. Chem. Eng. Data 2015, 60, 11, 3296-3299
ABSTRACT
The ternary system of NaH2PO4 + Na2SO4 + H2O at 323.15 K and 343.15 K is studied by the method of isothermal solution saturation. The equilibrium solid phases are investigated by the Schreinemaker s method of wet residues and verified by X-ray diffraction. The solubility of the system is determined. On the basis of the experimental data, the phase diagrams are plotted and the crystallization regions are determined. The phase equilibrium at different temperatures are compared and discussed. This comparison further illustrates that the temperature can influence the equilibrium of the ternary system. The research can offer meaningful data support for separation processes and further theoretical studies.
Compounds
# Formula Name
1 H2NaO4P sodium dihydrogen phosphate
2 Na2O4S sodium sulfate
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 3
  • 2
  • Mass fraction - 2 ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Titration method
  • 5
  • POMD
  • 1
  • 3
  • 2
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Titration method
  • 28
  • POMD
  • 1
  • 3
  • 2
  • Mass fraction - 2 ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 5
  • POMD
  • 1
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Titration method
  • 1
  • POMD
  • 1
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 1
  • POMD
  • 3
  • 2
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Titration method
  • 2