Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

(Solid + Liquid) Phase Equilibrium in the Aqueous Ternary System NaH2PO4 + CO(NH2)2 + H2O at (308.15, 328.15, and 348.15) K

Xiao, Y.[Yang], Su, J.-l.[Jun-lin], Cao, H.[Haitao]
J. Chem. Eng. Data 2015, 60, 7, 2162-2166
ABSTRACT
In this study, the solubility of the ternary system (NaH2PO4 + CO(NH2)2 + H2O) at (308.15, 328.15, and 348.15) K were determined, using isothermal solution saturation. The equilibrium solid phases were analyzed by the Schreinemaker s method of wet residues and verified by X-ray diffraction (XRD). According to the experimental data, the phase diagrams were plotted and the crystallization areas were determined. The phase equilibrium at different temperatures were compared and discussed. This research provides an accurate answer for whether crystalline hydrate and urea phosphate exist in this system or not. All results can offer fundamental data for crystallization processes and further theoretical studies.
Compounds
# Formula Name
1 H2NaO4P sodium dihydrogen phosphate
2 CH4N2O urea
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • 3
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Titration method
  • 22
  • POMD
  • 2
  • 1
  • 3
  • Mass fraction - 2 ; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Titration method
  • 9
  • POMD
  • 2
  • 1
  • 3
  • Mass fraction - 2 ; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal of intercomponent compound 2
  • Titration method
  • 7
  • POMD
  • 2
  • 1
  • 3
  • Mass fraction - 2 ; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 8
  • POMD
  • 2
  • 1
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal of intercomponent compound 1
  • Gravimetric
  • 2
  • POMD
  • 2
  • 1
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal of intercomponent compound 2
  • Gravimetric
  • 2
  • POMD
  • 2
  • 1
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal - 1
  • Gravimetric
  • 2
  • POMD
  • 2
  • 1
  • 3
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal of intercomponent compound 1
  • Titration method
  • 2
  • POMD
  • 2
  • 1
  • 3
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal of intercomponent compound 2
  • Titration method
  • 2
  • POMD
  • 2
  • 1
  • 3
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal - 1
  • Titration method
  • 2
  • POMD
  • 2
  • 3
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Titration method
  • 3
  • POMD
  • 1
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Titration method
  • 1
  • POMD
  • 1
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 2
  • Titration method
  • 1
  • POMD
  • 1
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 1