Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities, viscosities and conductivities of the imidazolium ionic liquids [Emim][Ac], [Emim][FAP], [Bmim][BETI], [Bmim][FSI], [Hmim][TFSI], and [Omim][TFSI]

Nazet, A.[Andreas], Sokolov, S.[Sophia], Sonnleitner, T.[Thomas], Makino, T.[Takashi], Kanakubo, M.[Mitsuhiro], Buchner, R.[Richard]
J. Chem. Eng. Data 2015, 60, 8, 2400-2411
ABSTRACT
Data for the transport properties electrical conductivity, ?, and dynamic viscosity, ?, of the imidazolium ionic liquids [Emim][FAP], [Emim][Ac], [Bmim][BETI], [Bmim][FSI], [Hmim][TFSI], and [Omim][TFSI] (? only) is presented. Electrical conductivity has been studied in the wide temperature range of (273.15 to 468.15) K, whereas ? was determined in the range of (273.15 to 408.15) K. The data could be well fitted by the empirical Vogel Fulcher Tammann equation. Additionally, the densities of these ionic liquids, showing a linear dependence on temperature, were collected from (273.15 to 363.15) K.
Compounds
# Formula Name
1 C8H14N2O2 1-ethyl-3-methylimidazolium acetate
2 C12H11F18N2P 1-ethyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate
3 C12H15F10N3O4S2 1-butyl-3-methylimidazolium bis(perfluoroethylsulfonyl)imide
4 C8H15F2N3O4S2 1-butyl-3-methylimidazolium bis(fluorosulfonyl)imide
5 C12H19F6N3O4S2 1-hexyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide
6 C14H23F6N3O4S2 1-octyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • SPHERE:UFactor:8
  • 14
  • POMD
  • 1
  • Electrical conductivity, S/m ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Alternating current cell with electrodes
  • 13
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • SPHERE:UFactor:2
  • 13
  • POMD
  • 2
  • Electrical conductivity, S/m ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Alternating current cell with electrodes
  • 20
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 13
  • POMD
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CONCYL:UFactor:2
  • 13
  • POMD
  • 3
  • Electrical conductivity, S/m ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Alternating current cell with electrodes
  • 29
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 13
  • POMD
  • 4
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CONCYL:UFactor:2
  • 13
  • POMD
  • 4
  • Electrical conductivity, S/m ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Alternating current cell with electrodes
  • 29
  • POMD
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 18
  • POMD
  • 5
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CONCYL:UFactor:2
  • 14
  • POMD
  • 5
  • Electrical conductivity, S/m ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Alternating current cell with electrodes
  • 20
  • POMD
  • 6
  • Electrical conductivity, S/m ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Alternating current cell with electrodes
  • 29