Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density and Viscosity of Partially Carbonated Aqueous Tertiary Alkanolamine Solutions at Temperatures between (298.15 and 353.15) K

Zhang, J.[Jiafei], Fennell, P. S.[Paul S.], Trusler, J. P. M.
J. Chem. Eng. Data 2015, 60, 8, 2392-2399
ABSTRACT
The density and viscosity of partially carbonated aqueous solutions of either 2-dimethylaminoethanol or 2-diethylaminoethanol were measured over a temperature range of (298.15 to 353.15) K with alkanolamine mass fractions of 0.15 to 0.45. Correlations were developed to represent the density and viscosity of these solutions as a function of amine concentration, CO2 loading, and temperature. For the density, the correlation represents the experimental data to within +- 0.2 %, while the viscosity data were correlated to within +- 4 %. The data and models reported in this paper will help facilitate a better understanding of the performance of these amines in CO2 capture processes, especially in relation to mass transfer and hydrodynamic calculations.
Compounds
# Formula Name
1 C2H7NO 2-aminoethan-1-ol
2 C4H11NO 2-(N,N-dimethylamino)ethanol
3 C6H15NO (diethylamino)ethanol
4 CO2 carbon dioxide
5 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 7
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 7
  • POMD
  • 4
  • 1
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Mass fraction - 1; Liquid
  • Liquid
  • Vibrating tube method
  • 42
  • POMD
  • 4
  • 1
  • 5
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Mass fraction - 1; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 30
  • POMD
  • 2
  • 4
  • 5
  • Mass density, kg/m3 ; Liquid
  • Solvent: Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 82
  • POMD
  • 2
  • 4
  • 5
  • Viscosity, Pa*s ; Liquid
  • Solvent: Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 63
  • POMD
  • 3
  • 4
  • 5
  • Mass density, kg/m3 ; Liquid
  • Solvent: Mass fraction - 3; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 90
  • POMD
  • 3
  • 4
  • 5
  • Viscosity, Pa*s ; Liquid
  • Solvent: Mass fraction - 3; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 70
  • POMD
  • 1
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mass fraction - 1; Liquid
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 1
  • 5
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mass fraction - 1; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 7
  • POMD
  • 2
  • 5
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 23
  • POMD
  • 2
  • 5
  • Viscosity, Pa*s ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 18
  • POMD
  • 3
  • 5
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 21
  • POMD
  • 3
  • 5
  • Viscosity, Pa*s ; Liquid
  • Mass fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 18