Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility Measurement and Correlation of Isobutane with Two Pentaerythritol Tetraalkyl Esters between (293.15 and 348.15) K

Sun, Y.[Yanjun], Wang, X.[Xiaopo], Gong, N.[Na], Liu, Z.[Zhigang]
J. Chem. Eng. Data 2015, 60, 5, 1504-1509
ABSTRACT
The solubilities of isobutane (R600a) in pentaerythritol tetrapentanoate (PEC5) and in pentaerythritol tetraheptanoate (PEC7) between (293.15 and 348.15) K have been measured based on the isochoric saturation method. The experimental solubility data were correlated by using the Peng Robinson equation of state with the LCVM mixing rule in which the excess Gibbs energy at infinite pressure was represented by the van Laar equation. The absolute average deviation and maximum absolute deviation of the pressure from the correlated results was 1.18 % and 3.27 % for R600a + PEC5 system, respectively. For the R600a + PEC7 system, the absolute average deviation and maximum absolute deviation of pressure was 0.92 % and 2.17 %.
Compounds
# Formula Name
1 C4H10 2-methylpropane
2 C25H44O8 pentaerythritol tetrapentanoate
3 C33H60O8 pentaerythritol tetraheptanoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • pressure drop on dissolution
  • 49
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • pressure drop on dissolution
  • 49