The heat capacity of Pt(C5H7O2)2 molecular crystal was measured in the temperature range of 239 515 K. Using data on the heat capacity, the most important thermodynamic and physical characteristics of Pt(C5H7O2)2 were obtained. The density of states g(u) and characteristic temperatures related to the moments of the g(u) were obtained. We demonstrate the possibility to calculate the molar zero-point energy from the experiment with high accuracy. The isobaric thermodynamic functions (entropy, enthalpy and reduced Gibbs energy) were calculated. Using the information about g(u), the isochoric thermodynamic functions (heat capacity, entropy, internal energy and reduced Helmholtz energy) up to the melting point were calculated. The knowledge of zero-point energy allowed calculating the total enthalpy and total internal energy of Pt(C5H7O2)2. A detailed analysis of the accuracy of the obtained characteristics was provided. The approach used to obtain the important characteristics of solids is general and can be used to study a wide range of objects.
Compounds
#
Formula
Name
1
C10H14O4Pt
platinum acetylacetonate
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.
Type
Compound-#
Property
Variable
Constraint
Phase
Method
#Points
POMD
1
Normal melting temperature, K ; Crystal
Crystal
Liquid
Air at 1 atmosphere
DTA
1
POMD
1
Molar heat capacity at constant pressure, J/K/mol ; Crystal