Thermodynamics Research Center / ThermoML | Thermochimica Acta

Studies on solution crystallization of Na2SO4*10H2O embedded in porous polyurethane foam for thermal energy storage application

Purohit, B.K., Sistla, V.S.
Thermochim. Acta 2018, 668, 9-18
ABSTRACT
Inorganic salt hydrates as a phase change material have the advantage of high latent heat values, high thermal conductivity and are not flammable. Phase segregation is the key downside feature that restricts its application in thermal energy storage application. A PU-PCM composite was prepared by incorporating aqueous saturated sodium sulphate solution, inorganic phase change material (PCM), within open pores of polyurethane (PU) foam. Experimental study on the thermal insulation performance of this composite, aqueous sodium sulphate solution embedded in open cell polyurethane foam, was discussed. This paper presents the computational solving approach for the thermal analysis of this composite having crystallization of sodium sulphate decahydrate, from its aqueous solution, within open pores of PU foam. Thermal study of salt solution in a porous material that undergoes phase change was done using COMSOL Multiphysics software and results were compared with experimental result.
Compounds
# Formula Name
1 H20Na2O14S sodium sulfate decahydrate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Normal melting temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DTA:corrimp
  • 1
  • POMD
  • 1
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DSC
  • 1