Thermodynamics Research Center / ThermoML | Thermochimica Acta

Low cost apparatus for rapid boiling point determination of small air sensitive samples under inert atmosphere

Herbig, Marcus, Kroke, Edwin
Thermochim. Acta 2017, 654, 81-84
ABSTRACT
The boiling point is a characteristic property of substances and mixtures. We have developed a new low cost apparatus which uses standard Schlenk technique for measuring the boiling point of small samples (less than 0.2 ml) under inert atmosphere.
Compounds
# Formula Name
1 C4H10O diethyl ether
2 C5H12 pentane
3 CH2Cl2 dichloromethane
4 C4H8O tetrahydrofuran
5 CHCl3 trichloromethane
6 CH4O methanol
7 C6H14 hexane
8 C6H6 benzene
9 C7H8 toluene
10 C2H6OS dimethyl sulfoxide
11 C6H19NSi2 1,1,1,3,3,3-hexamethyldisilazane
12 C7H17NOSi trimethylmorpholinosilane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1
  • POMD
  • 2
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1
  • POMD
  • 3
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1
  • POMD
  • 4
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1
  • POMD
  • 5
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1
  • POMD
  • 6
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1
  • POMD
  • 7
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1
  • POMD
  • 8
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1
  • POMD
  • 9
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1
  • POMD
  • 10
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1
  • POMD
  • 11
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1
  • POMD
  • 12
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Distillation
  • 1