Name: ThermoML Representation of Published Experimental Data from Thermochimica Acta (0040-6031, Elsevier)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

The enthalpies of solution of diglyme, triglyme, tetraglyme, pentaglyme and hexaglyme in N,N-dimethylforamide-methanol mixtures (DMF+MeOH) have been measured at 298.15 K. On the basis of the obtained data, the effect of the acid-base properties of the DMF+MeOH mixtures on the standard solution enthalpy of glymes in this mixtures has been analyzed. The obtained results have been compared with analogous data obtained in N,N-dimethylformamide-water (DMF+W) mixtures.

Compounds

#	Formula	Name
1	C6H14O3	2,5,8-trioxanonane
2	C8H18O4	2,5,8,11-tetraoxadodecane
3	C10H22O5	2,5,8,11,14-pentaoxapentadecane
4	C12H26O6	2,5,8,11,14,17-hexaoxaoctadecane
5	C14H30O7	2,5,8,11,14,17,20-heptaoxaheneicosane
6	CH4O	methanol
7	C3H7NO	dimethylformamide

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	6 7 1	Molar enthalpy of solution, kJ/mol ; Liquid	Solvent: Mole fraction - 6; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 1; Liquid	Liquid	ISOPERIBOL	10
POMD	6 7 2	Molar enthalpy of solution, kJ/mol ; Liquid	Solvent: Mole fraction - 6; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 2; Liquid	Liquid	ISOPERIBOL	10
POMD	6 7 3	Molar enthalpy of solution, kJ/mol ; Liquid	Solvent: Mole fraction - 6; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 3; Liquid	Liquid	ISOPERIBOL	10
POMD	6 7 4	Molar enthalpy of solution, kJ/mol ; Liquid	Solvent: Mole fraction - 6; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 4; Liquid	Liquid	ISOPERIBOL	10
POMD	6 7 5	Molar enthalpy of solution, kJ/mol ; Liquid	Solvent: Mole fraction - 6; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 5; Liquid	Liquid	ISOPERIBOL	10
POMD	6 1	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 1; Liquid		Liquid	ISOPERIBOL	1
POMD	6 2	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 2; Liquid		Liquid	ISOPERIBOL	1
POMD	6 3	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 3; Liquid		Liquid	ISOPERIBOL	1
POMD	6 4	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 4; Liquid		Liquid	ISOPERIBOL	1
POMD	6 5	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 5; Liquid		Liquid	ISOPERIBOL	1
POMD	7 1	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 1; Liquid		Liquid	ISOPERIBOL	1
POMD	7 2	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 2; Liquid		Liquid	ISOPERIBOL	1
POMD	7 3	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 3; Liquid		Liquid	ISOPERIBOL	1
POMD	7 4	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 4; Liquid		Liquid	ISOPERIBOL	1
POMD	7 5	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Mole fraction - 5; Liquid		Liquid	ISOPERIBOL	1

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Effect of properties of the N,N-dimethylformamide-methanol and N,N-dimethylformamide-water mixtures on the solution enthalpy of glymes in these mixtures at 298.15 K

Jozwiak, M.[Malgorzata], Szylberg, M.[Magdalena], Piekarski, H.[Henryk], Kustrzepa, K.[Kinga], Jozwiak, A.[Andrzej]

ABSTRACT