Lithium cobaltite LiCoO2 was prepared by solid state route and characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), magnetic properties measurement and simultaneous thermal analysis (STA). The heat capacity and enthalpy increments were measured by physical property measurement system (PPMS), differential scanning calorimetry (DSC) and drop calorimetry. The oxygen non-stoichiometry was determined using thermogravimetric measurement (TG). Above room temperature the temperature dependence of the molar heat capacity was derived by simultaneous least squares method from DSC and enthalpy data. The heat capacity was also analyzed in terms of a combined Debye-Einstein model. The molar entropy was evaluated from the low temperature heat capacity data.
Compounds
#
Formula
Name
1
CoLiO2
cobalt lithium oxide (LiCoO2)
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.
Type
Compound-#
Property
Variable
Constraint
Phase
Method
#Points
POMD
1
Molar heat capacity at constant pressure, J/K/mol ; Crystal
Temperature, K; Crystal
Pressure, kPa; Crystal
Crystal
RELAXCAL
78
POMD
1
Molar heat capacity at constant pressure, J/K/mol ; Crystal