The integral molar mixing enthalpies of liquid Ga-Li-Zn alloys were determined by drop calorimetry and with the use of the Setaram MHTC 96 Line Evo calorimeter. The measurements for this ternary system were taken at four temperatures and six different alloy compositions: at 993 K the (Ga0.90Li0.10)1-xZnx and the (Ga0.75Li0.25)1-xZnx, at 1044 K the (Ga0.60Li0.40)1-xZnx, the (Ga0.50Li0.50)1-xZnx, the (Ga0.40Li0.60)1-xZnx, at 891 K and 1018 K the (Ga0.25Li0.75)1-xZnx. This study has begun the experimental measurements of the Ga-Li-Zn system and shows a comparison of previous literature data for binary Ga-Li system.
Compounds
#
Formula
Name
1
Ga
gallium
2
Li
lithium
3
Zn
zinc
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.
Type
Compound-#
Property
Variable
Constraint
Phase
Method
#Points
POMD
2
1
3
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
Temperature, K; Liquid
Mole fraction - 2; Liquid
Mole fraction - 3; Liquid
Pressure, kPa; Liquid
Liquid
Calvet calorimetry
72
POMD
2
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid