ABSTRACT

Enthalpies of solution at infinite dilution at 298 K, solnHA/Solvent, have been measured by isothermal solution calorimetry for 43 and 72 organic solutes dissolved in chlorobenzene and 1,2-dichlorobenzene, respectively. The measured solnHA/Solventdata, along with published solnHA/Solventvalues taken from the published literature for solutes dissolved in both chlorobenzene solvents, were converted to enthalpies of solvation, solvHA/Solvent, using standard thermodynamic equations. Abraham model correlations were developed from the experimental solvHA/Solventdata. The best derived correlations describe the experimental gas-to-chlorobenzene and gas-to-1,2-dichlorobenzene enthalpies of solvation to within standard deviations of 1.5 kJ mol-1and 1.9 kJ mol-1, respectively. Enthalpies of X H. . . (X O, N, and C) hydrogen bond formation of proton donor solutes (alcohols, amines, chlorinated hydrocarbons, etc.) with chlorobenzene and 1,2-dichlorobenzene were calculated based on the Abraham solvation equation. Obtained values are in good agreement with the results determined using conventional methods.

Compounds

#	Formula	Name
1	C3H6O	acetone
2	C6H5Cl	chlorobenzene
3	C7H5N	benzonitrile
4	C6H12O2	butyl ethanoate
5	C4H10O	butan-1-ol
6	C11H14O2	butyl benzoate
7	C4H7N	butanenitrile
8	C6H5ClO	2-chlorophenol
9	C10H22	decane
10	C10H22O	decan-1-ol
11	CH2Cl2	dichloromethane
12	C4H9NO	N,N-dimethylethanamide
13	C8H10O3	1,3-dimethoxy-2-hydroxybenzene
14	C12H26	dodecane
15	C4H8O2	ethyl acetate
16	C9H10O2	ethyl benzoate
17	C9H10O3	ethyl 2-hydroxybenzoate
18	C7H16	heptane
19	C7H14O	2-heptanone
20	C6H14O	hexan-1-ol
21	C8H7N	1H-indole
22	C9H12	1,3,5-trimethylbenzene
23	C7H8O2	2-methoxyphenol
24	C7H8O2	3-methoxyphenol
25	C7H8O2	4-methoxyphenol
26	C3H6O2	methyl ethanoate
27	C8H8O2	methyl benzoate
28	C4H8O2	methyl propanoate
29	C8H8O3	methyl 2-hydroxybenzoate
30	C9H20	nonane
31	C9H18O	2-nonanone
32	C8H18	octane
33	C8H16O	2-octanone
34	C8H18O	octan-1-ol
35	C5H12O	pentan-1-ol
36	C5H10O	pentan-2-one
37	C6H7N	3-methylpyridine
38	C6H7N	4-methylpyridine
39	C3H5N	propanenitrile
40	C5H10O2	propyl ethanoate
41	C10H12O2	propyl benzoate
42	C3H4N2	1H-pyrazole
43	CCl4	tetrachloromethane
44	CHCl3	trichloromethane
45	C2H3N	acetonitrile
46	C6H4Cl2	1,2-dichlorobenzene
47	C8H8O	acetophenone
48	C7H8O	anisole
49	C6H7N	aniline
50	C14H10	anthracene
51	C13H10O	benzophenone
52	C12H10	biphenyl
53	C6H5Br	bromobenzene
54	C4H8O	butanone
55	C4H9Cl	1-chlorobutane
56	C8H18O	dibutyl ether
57	C3H6Cl2	1,2-dichloropropane
58	C4H8O2	1,4-dioxane
59	C4H10O	diethyl ether
60	C3H7NO	dimethylformamide
61	C2H6O	ethanol
62	C6H5F	fluorobenzene
63	C6H14	hexane
64	C8H8O2	2-hydroxyacetophenone
65	CH4O	methanol
66	C10H8	naphthalene
67	C6H7N	2-methylpyridine
68	C3H8O	propan-1-ol
69	C5H5N	pyridine
70	C4H8O	tetrahydrofuran
71	C12H27N	tributylamine
72	C8H10	1,2-dimethylbenzene
73	C8H10	1,3-dimethylbenzene
74	C8H10	1,4-dimethylbenzene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	1 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 1; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	3 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 3; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 4	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 4; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	5 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 5; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 6	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 6; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 7	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 7; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	8 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 8; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 9	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 9; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 10	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 10; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	11 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 11; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 12	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 12; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	13 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 13; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	2 14	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 14; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 15	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 15; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	16 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 16; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 17	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 17; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 18	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 18; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 19	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 19; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 20	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 20; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 21	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 21; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	22 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 22; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	23 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 23; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 24	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 24; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 25	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 25; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	26 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 26; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	27 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 27; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 28	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 28; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 29	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 29; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 30	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 30; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 31	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 31; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 32	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 32; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 33	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 33; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 34	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 34; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	35 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 35; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	36 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 36; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 37	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 37; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	38 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 38; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	39 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 39; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 40	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 40; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 41	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 41; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	2 42	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 42; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	43 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 43; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	44 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 44; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	45 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 45; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	1 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 1; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 47	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 47; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 48	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 48; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	49 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 49; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 50	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 50; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	46 3	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 3; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 51	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 51; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	52 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 52; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	46 53	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 53; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	54 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 54; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	5 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 5; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 4	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 4; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 6	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 6; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 7	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 7; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 2	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 2; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 55	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 55; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 8	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 8; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 9	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 9; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 10	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 10; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 56	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 56; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	57 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 57; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 58	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 58; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 14	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 14; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	11 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 11; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	59 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 59; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	13 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 13; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	46 12	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 12; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	60 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 60; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	61 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 61; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 15	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 15; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	16 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 16; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 17	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 17; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 62	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 62; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 18	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 18; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 19	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 19; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 63	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 63; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 20	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 20; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 64	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 64; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 21	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 21; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	65 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 65; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	23 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 23; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 24	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 24; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 25	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 25; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	26 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 26; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	27 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 27; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 22	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 22; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 28	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 28; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 29	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 29; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	66 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 66; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	46 30	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 30; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 31	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 31; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 32	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 32; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 34	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 34; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 33	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 33; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 36	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 36; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	35 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 35; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 67	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 67; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 37	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 37; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 38	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 38; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	68 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 68; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 39	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 39; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 40	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 40; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 41	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 41; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 42	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 42; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	1
POMD	46 69	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 69; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 70	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 70; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 71	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 71; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	44 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 44; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	72 46	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 72; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 73	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 73; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1
POMD	46 74	Molar enthalpy of solution, kJ/mol ; Liquid	Mole fraction - 74; Liquid Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Titration calorimetry	1

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Effect of halogen substitution on the enthalpies of solvation and hydrogen bonding of organic solutes in chlorobenzene and 1,2-dichlorobenzene derived using multi-parameter correlations

Varfolomeev, M. A.[Mikhail A.], Rakipov, I. T.[Ilnaz T.], Khachatrian, A. A.[Artashes A.], Acree, Jr., W. E.[William E.], Brumfield, M.[Michela], Abraham, M. H.[Michael H.]

ABSTRACT