The densities, r and speeds of sound, u of D(-)-ribose in aqueous solutions of ammonium based protic ionic liquid i.e., 3-hydroxypropylammonium acetate (3HPAAc) have been measured at temperatures (298.15 318.15) K and at atmospheric pressure. These experimental data were used to calculate apparent molar volumes, V2,w, apparent molar isentropic compressibilities, Ks,2,w, infinite dilution partial molar volumes, V2 , and partial molar isentropic compressibilities, K s,2 and the corresponding volumes of transfer (DtV2 and DtK s,2). Both DtV2 and DtK s,2 values were found to be positive, which increase with cosolute (3HPAAc) concentration and temperature, which indicate the presence of hydrophilic-ionic types of interactions between D( )-ribose (Rib) and ions of 3HPAAc. Various derived parameters such as expansion coefficients, hydration numbers, pair and triplet interaction coefficients for Rib in aqueous 3HPAAc solutions have also been evaluated and discussed.
Compounds
#
Formula
Name
1
C5H10O5
D-ribose
2
C5H13NO3
3-hydroxypropylammonium acetate
3
H2O
water
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.
Type
Compound-#
Property
Variable
Constraint
Phase
Method
#Points
POMD
1
3
2
Mass density, kg/m3 ; Liquid
Solvent: Molality, mol/kg - 2; Liquid
Temperature, K; Liquid
Molality, mol/kg - 1; Liquid
Pressure, kPa; Liquid
Liquid
Vibrating tube method
120
POMD
1
3
2
Speed of sound, m/s ; Liquid
Solvent: Molality, mol/kg - 2; Liquid
Temperature, K; Liquid
Molality, mol/kg - 1; Liquid
Pressure, kPa; Liquid
Frequency, MHz; Liquid
Liquid
Sing-around technique in a fixed-path interferometer