Thermodynamics Research Center / ThermoML | Thermochimica Acta

The thermal physical properties and stability of the eutectic composition in a Na2CO3-NaCl binary system

Ye, L.[Longgang], Tang, C.[Chaobo], Chen, Y.[Yongming], Yang, S.[Shenghai], Tang, M.[Motang]
Thermochim. Acta 2014, 596, 14-20
ABSTRACT
The thermal physical properties of the eutectic Na2CO3-NaCl molten saltswere investigated. The melting point of the binary salt mixture was 909 K, the density of the molten salts decreased linearly with increased temperature, and the viscosity has an exponential relationship with temperature. The vapor pressure increases significantly as the temperature is increased. The thermal stability of the eutectic mixture was measured by weight loss. The results indicate that the degree of volatility has a linear relationship with time. The heating and cooling curves of the molten salt were almost invariant during the cycle times. The titration and XRD studies demonstrate that the composition and phase of the molten saltwere unchanged after high-temperature treatment. The morphology and content of the solid eutectic salts were observed by SEM-BSE and EDX. From this study, it can be concluded that the thermo-physical properties and thermal stability were excellent below 1073 K.
Compounds
# Formula Name
1 CNa2O3 sodium carbonate
2 ClNa sodium chloride
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Eutectic temperature, K ; Crystal - 1
  • Crystal - 1
  • Crystal - 2
  • Liquid
  • Air at 1 atmosphere
  • DTA
  • 1
  • POMD
  • 1
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • CONCYL:UFactor:5
  • 5
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Buoyancy - hydrostatic balance
  • 7