ABSTRACT

The magnetic effect on the phase transitions of n-C22H46(docosane) was measured using a high resolution and super-sensitive DSC. The surface freezing phenomenon was observed at about 3 K above the bulk melting temperature in addition to solid solid transitions and melting transition. The transition temperatures due to the solid solid transitions and melting were shifted to higher temperatures by about 10 mK by applying magnetic field of 5T. On the other hand, the transition temperature due to surface freezing phenomenon was shifted to lower temperature by about 10 mK by applying magnetic field of 5T. The magnetic effects were discussed based on the extension of the Clapeyron equation.

Compounds

#	Formula	Name
1	C22H46	docosane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Phase	Method	#Points
POMD	1	Triple point temperature, K ; Crystal 2	Crystal 2 Crystal 1 Air at 1 atmosphere	DTA	1
POMD	1	Triple point temperature, K ; Crystal 1	Crystal 1 Liquid Air at 1 atmosphere	DTA	1
POMD	1	Molar enthalpy of transition or fusion, kJ/mol ; Crystal 2	Crystal 2 Crystal 1 Air at 1 atmosphere	DSC	1
POMD	1	Molar enthalpy of transition or fusion, kJ/mol ; Crystal 1	Crystal 1 Liquid Air at 1 atmosphere	DSC	1

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Magnetic effect on the phase transitions of n-docosane by means of a high resolution and super-sensitive DSC

Wang, S.[Shaolan], Tozaki, K.-I.[Ken-Ichi], Hayashi, H.[Hideko], Inaba, H.[Hideaki]

ABSTRACT