ABSTRACT

tExcess molar enthalpies, HEijkof 1-ethyl-3-methylimidazolium tetrafluoroborate (i) + 2-methylaniline(j) + pyridine or - or - or -picoline (k) ternary mixtures have been measured over an entire mole frac-tion at 298.15 K using micro differential scanning calorimeter [Model- DSC 7 Evo]. The Redlich Kisterequation parameters have been fitted to measured data. The HEijkvalues for the studied mixtures are neg-ative over entire composition range. The topology of the constituents of the mixtures has been utilizedto (Graph theory) predict HEijkvalues of the investigated mixtures. It has been observed that HEijkvaluesdetermined by Graph theory compare well with their corresponding experimental values.

Compounds

#	Formula	Name
1	C6H11BF4N2	1-ethyl-3-methylimidazolium tetrafluoroborate
2	C7H9N	2-methylaniline
3	C5H5N	pyridine
4	C6H7N	2-methylpyridine
5	C6H7N	3-methylpyridine
6	C6H7N	4-methylpyridine

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2 3 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calvet calorimetry	25
POMD	2 4 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calvet calorimetry	25
POMD	2 5 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calvet calorimetry	25
POMD	2 6 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calvet calorimetry	25

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Excess molar enthalpies of ternary mixtures containing1-ethyl-3-methylimidazolium tetrafluoroborate and organic solvents

Sharma, V. K., Solanki, S., Bhagour, S., Sharma, D.

ABSTRACT