Thermodynamics Research Center / ThermoML | Thermochimica Acta

Solubility, dissolution enthalpy and entropy of L-Glutamine in mixed solvents of ethanol+water and acetone+water

Yu, Q.[Qiushuo], Ma, X.[Xiaoxun], Xu, L.[Long]
Thermochim. Acta 2013, 558, 6-9
ABSTRACT
The solubilities of L-Glutamine in mixed solvents (ethanol+water, acetone+water) were determined at temperatures between 278 K and 313 K. The experimental data were correlated with the Apelblat model. The calculated values of Apelblat model were found to show a fine representation of the experimental data. Then the dissolution enthalpy and entropy of L-Glutamine were predicted from the solubility data using van't Hoff equation.
Compounds
# Formula Name
1 C5H10N2O3 L-glutamine
2 C2H6O ethanol
3 H2O water
4 C3H6O acetone
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 4
  • 3
  • Mole fraction - 1 ; Liquid
  • Solvent: Amount ratio of component to other component of binary solvent - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Phase equilibration
  • 24
  • POMD
  • 1
  • 2
  • 3
  • Mole fraction - 1 ; Liquid
  • Solvent: Amount ratio of component to other component of binary solvent - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Phase equilibration
  • 24
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Phase equilibration
  • 8