Thermodynamics Research Center / ThermoML | Thermochimica Acta

Correlation and prediction of the phase behavior and thermal properties of binary and ternary systems of 2,2 -oxybis[propane] + benzene, toluene, cyclohexane or n-heptane

Didaoui, S.[Saeda], Ait-Kaci, A.[Ahmed]
Thermochim. Acta 2013, 567, 46-50
ABSTRACT
The experimental excess molar enthalpies data of liquid binary and ternary mixtures of DIPE with benzene, toluene, cyclohexane and n-heptane have been measured at 303.15 K and constant pressure using a Calvet type microcalorimeter, C80 (Setaram, France). A Redlich Kister type equation was used to correlate experimental values. The theoretical results obtained by the DISQUAC model are significantly closer to the experimental values.
Compounds
# Formula Name
1 C6H14O diisopropyl ether
2 C6H6 benzene
3 C7H8 toluene
4 C7H16 heptane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 3
  • Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Calvet calorimetry
  • 3
  • POMD
  • 2
  • 4
  • Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Calvet calorimetry
  • 3
  • POMD
  • 2
  • 1
  • 3
  • Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
  • Mole fraction - 3; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Calvet calorimetry
  • 40
  • POMD
  • 2
  • 1
  • 4
  • Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
  • Mole fraction - 2; Liquid
  • Mole fraction - 4; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Calvet calorimetry
  • 24