ABSTRACT

Precise measurement of electrolytic conductance ( (C)), density ( I), viscosity ( A), refractive index (nD) and ultrasonic speed (u) of lithium halides LiX (where X = Cl, Br, I) have been studied in different mass fraction (w1= 0.00 - 0.75) of acetonitrile (ACN) + 1,3-dioxolane (1,3-DO) solvent mixtures at 298.15K. The limiting molar conductivity ( (C)o), association constant (KA), and distance of closest approach of ions (R) have been evaluated using Fuoss-conductance equation (1978). The deviation of conductometric curve ( (C) vs ac) from linearity in 1,3-DO, indicates triple-ion formation, analyzed by the Fuoss-Kraus theory. The limiting apparent molar volume ( ), experimental slope ( ) derived from Masson equation, and viscosity B and A-coefficients derived from Jones-Dole equation supplemented with density and viscosity data respectively have been interpreted in terms of ion-solvent and ion-ion interactions. The limiting partial molar adiabatic compressibility ( ) and experimental slopes ( ), have also been obtained from the value of speed of sound (u) and discussed to interpret the same.

Compounds

#	Formula	Name
1	C2H3N	acetonitrile
2	C3H6O2	1,3-dioxolane
3	ClLi	lithium chloride
4	BrLi	lithium bromide
5	ILi	lithium iodide

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	1 2	Viscosity, Pa*s ; Liquid	Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	5
POMD	1 2	Refractive index (Na D-line) ; Liquid	Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	5
POMD	1 2	Speed of sound, m/s ; Liquid	Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	5
POMD	1 2	Mass density, kg/m3 ; Liquid	Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	5
POMD	2 3	Molar conductivity, S*m2/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Alternating current cell with electrodes	12
POMD	2 3	Viscosity, Pa*s ; Liquid	Amount concentration (molarity), mol/dm3 - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	6
POMD	2 3	Refractive index (Na D-line) ; Liquid	Amount concentration (molarity), mol/dm3 - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	6
POMD	2 3	Speed of sound, m/s ; Liquid	Amount concentration (molarity), mol/dm3 - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	6
POMD	2 3	Mass density, kg/m3 ; Liquid	Amount concentration (molarity), mol/dm3 - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	6
POMD	2 4	Molar conductivity, S*m2/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Alternating current cell with electrodes	12
POMD	2 4	Viscosity, Pa*s ; Liquid	Amount concentration (molarity), mol/dm3 - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	6
POMD	2 4	Refractive index (Na D-line) ; Liquid	Amount concentration (molarity), mol/dm3 - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	6
POMD	2 4	Speed of sound, m/s ; Liquid	Amount concentration (molarity), mol/dm3 - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	6
POMD	2 4	Mass density, kg/m3 ; Liquid	Amount concentration (molarity), mol/dm3 - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	6
POMD	2 5	Molar conductivity, S*m2/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Alternating current cell with electrodes	12
POMD	2 5	Viscosity, Pa*s ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	6
POMD	2 5	Refractive index (Na D-line) ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	6
POMD	2 5	Speed of sound, m/s ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	6
POMD	2 5	Mass density, kg/m3 ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	6
POMD	1 2 3	Molar conductivity, S*m2/mol ; Liquid	Solvent: Mass fraction - 1; Liquid Amount concentration (molarity), mol/dm3 - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Alternating current cell with electrodes	48
POMD	1 2 3	Viscosity, Pa*s ; Liquid	Amount concentration (molarity), mol/dm3 - 3; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	24
POMD	1 2 3	Refractive index (Na D-line) ; Liquid	Amount concentration (molarity), mol/dm3 - 3; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	24
POMD	1 2 3	Speed of sound, m/s ; Liquid	Amount concentration (molarity), mol/dm3 - 3; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	24
POMD	1 2 3	Mass density, kg/m3 ; Liquid	Amount concentration (molarity), mol/dm3 - 3; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	24
POMD	1 2 4	Molar conductivity, S*m2/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 4; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Alternating current cell with electrodes	48
POMD	1 2 4	Viscosity, Pa*s ; Liquid	Amount concentration (molarity), mol/dm3 - 4; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	24
POMD	1 2 4	Refractive index (Na D-line) ; Liquid	Amount concentration (molarity), mol/dm3 - 4; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	24
POMD	1 2 4	Speed of sound, m/s ; Liquid	Amount concentration (molarity), mol/dm3 - 4; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	24
POMD	1 2 4	Mass density, kg/m3 ; Liquid	Amount concentration (molarity), mol/dm3 - 4; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	24
POMD	1 2 5	Molar conductivity, S*m2/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid Solvent: Volume fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Alternating current cell with electrodes	48
POMD	1 2 5	Viscosity, Pa*s ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	24
POMD	1 2 5	Refractive index (Na D-line) ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	24
POMD	1 2 5	Speed of sound, m/s ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	24
POMD	1 2 5	Mass density, kg/m3 ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid Solvent: Mass fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	24

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Physics and Chemistry of Lithium Halides in 1,3-Dioxolane and Its Binary Mixtures with Acetonitrile probed by Conductometric, Volumetric, Viscometric, Refractometric and Acoustic Study

Roy, M. N.[Mahendra Nath], Ekka, D.[Deepak], Banik, I.[Ishani], Majumder, A.

ABSTRACT