Name: ThermoML Representation of Published Experimental Data from Thermochimica Acta (0040-6031, Elsevier)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

Molar solution enthalpies of AgNO3, CsNO3, AgCs(NO3)2 and Ag3Cs(NO3)4, were measured in pure water at 298.15 K, using different calorimeters. The corresponding molar solution enthalpies at infinite dilution are then used to derive the standard enthalpies of formation of the AgCs(NO3)2 and Ag3Cs(NO3)4 compounds respectively as -7.34 and - 9.33 kJ/mol. Keywords: AgCs(NO3)2, Ag3Cs(NO3)4, dissolution, infinite dilution, enthalpies of formation.

Compounds

#	Formula	Name
1	Ag	silver
2	Cs	cesium
3	N2	nitrogen
4	O2	oxygen
5	AgNO3	silver nitrate
6	CsNO3	cesium nitrate
7	AgCsN2O6	cesium silver nitrate (1:1)
8	Ag3CsN4O12	cesium silver nitrate (1:3)
9	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	7	Normal melting temperature, K ; Crystal			Crystal Liquid Air at 1 atmosphere	VISOBS	1
POMD	8	Normal melting temperature, K ; Crystal			Crystal Liquid Air at 1 atmosphere	VISOBS	1
POMD	9 5	Molar enthalpy of solution, kJ/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ISOPERIBOL	4
POMD	9 5	Molar enthalpy of solution, kJ/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calset Calorimeter	10
POMD	9 6	Molar enthalpy of solution, kJ/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 6; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calset Calorimeter	11
POMD	9 6	Molar enthalpy of solution, kJ/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 6; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calvet calorimetry	5
POMD	7 9	Molar enthalpy of solution, kJ/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 7; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calset Calorimeter	7
POMD	7 9	Molar enthalpy of solution, kJ/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 7; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calvet calorimetry	4
POMD	8 9	Molar enthalpy of solution, kJ/mol ; Liquid	Amount concentration (molarity), mol/dm3 - 8; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calset Calorimeter	10
RXND	7 1 2 3 4	Molar enthalpy of reaction, kJ/mol				Solution calorimetry	1
RXND	8 1 2 3 4	Molar enthalpy of reaction, kJ/mol				Solution calorimetry	1
RXND	7 5 6	Molar enthalpy of reaction, kJ/mol				Solution calorimetry	1
RXND	8 5 6	Molar enthalpy of reaction, kJ/mol				Solution calorimetry	1

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Standard enthalpies of formation of the AgCs(NO3)2 and Ag3Cs(NO3)4 compounds

Hellali, D., Zoro, E., Boa, D., Zamali, H., Rogez, J., Jemal, M.

ABSTRACT