ABSTRACT

In this study, a novel fructose-based DES of choline chloride (2-hydroxyethyltrimethylammonium) has been synthesized at different molar ratios. The physical properties of density, viscosity, surface tension, refractive index and pH were measured and analyzed as function of various temperatures (25-85oC). The analysis of these physical properties revealed that these new DESs have the potential to be utilized for possible industrial applications involving processing and separation of food constituents. The suggested DESs have many desirable characteristics, e.g. they have low vapor pressure, inflammable, biodegradable, and made from renewable resources. The use of these DESs will positively affect the environment and make use of available renewable resources.

Compounds

#	Formula	Name
1	C5H14ClNO	choline chloride
2	C6H12O6	D-fructose

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2 1	Solid-liquid equilibrium temperature, K ; Liquid	Amount ratio of solute to solvent - 1; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 2	VISOBS	2
POMD	2 1	Solid-liquid equilibrium temperature, K ; Liquid	Amount ratio of solute to solvent - 1; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	VISOBS	2
POMD	2 1	Surface tension liquid-gas, N/m ; Liquid	Amount ratio of solute to solvent - 1; Liquid Temperature, K; Liquid		Liquid Air at 1 atmosphere	Ring tensiometer	28
POMD	2 1	Viscosity, Pa*s ; Liquid	Amount ratio of solute to solvent - 1; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Concentric cylinders viscometry	28
POMD	2 1	Refractive index (Na D-line) ; Liquid	Amount ratio of solute to solvent - 1; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	28
POMD	2 1	Mass density, kg/m3 ; Liquid	Amount ratio of solute to solvent - 1; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	28

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Fruit Sugar-based Deep Eutectic Solvents and their Physical Properties

Hayyan, A.[Adeeb], Mjalli, F. S.[Farouq S.], AlNashef, I.[Inas], Al-Wahaibi, T.[Talal], Al-Wahaibi, Y. M.[Yahya M.], Hashim, M. A.[Mohd Ali]

ABSTRACT