Thermodynamics Research Center / ThermoML | Thermochimica Acta

Solubilities of succinimide in different pure solvents and binary methanol+ethyl acetate solvent mixtures

Wang, K.[Kai], Hu, Y.-H.[Yong-Hong], Yang, W.-g.[Wen-ge], Shi, Y.[Ying], Li, Y.[Yonglan]
Thermochim. Acta 2012, 538, 79-85
ABSTRACT
Solubility data were measured for succinimide in pure ethyl acetate, acetonitrile, ethanol, acetone, tetrahydrofuran, methanol, isopropanol, n-butanol and binary methanol+ethyl acetate solvent mixtures at the temperature range between 278.2K and 325.1K under atmospheric pressure by gravimetric method. The solubilities of succinimide in those selected solvents increased with increasing temperature. The solubility data were correlated with the modified Apelblat equation to obtain the model parameters. The experimental results could be useful for optimizing the process of purification of succinimide in industry. Methanol could be the excellent solvent in the crystallization of succinimide.
Compounds
# Formula Name
1 C4H5NO2 succinimide
2 C4H8O2 ethyl acetate
3 C2H3N acetonitrile
4 C2H6O ethanol
5 C3H6O acetone
6 C4H8O tetrahydrofuran
7 CH4O methanol
8 C3H8O propan-2-ol
9 C4H10O butan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric method
  • 11
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 11
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 11
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetrcic
  • 11
  • POMD
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 11
  • POMD
  • 7
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 11
  • POMD
  • 8
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 11
  • POMD
  • 9
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 11
  • POMD
  • 7
  • 1
  • 2
  • Mole fraction - 1 ; Liquid
  • Mass fraction - 7; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • gravimetric
  • 55