ABSTRACT

Densities, speeds of sound and refractive indices at atmospheric pressure and at a temperature range of 283.15 K to 313.15 K, and isothermal vapour liquid equilibrium at 298.15 K for the binary mixtures of n-hexane or n-heptane with 1-chloropropane have been determined. Excess volumes, excess isentropic compressibilities, refractive index deviations and excess Gibbs functions were calculated from the experimental data. All these properties provide an insight into the nature of interactions operating on the present systems.

Compounds

#	Formula	Name
1	C6H14	hexane
2	C3H7Cl	1-chloropropane
3	C7H16	heptane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	7
POMD	1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	7
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	7
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	7
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	7
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	7
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	7
POMD	3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	7
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	7
POMD	1 2	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	13
POMD	1 2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	77
POMD	1 2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	77
POMD	1 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	77
POMD	1 2	Mole fraction - 1 ; Gas	Mole fraction - 1; Liquid	Temperature, K; Liquid	Gas Liquid	Density calibration data	13
POMD	3 2	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	13
POMD	3 2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	77
POMD	3 2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	77
POMD	3 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	77
POMD	3 2	Mole fraction - 3 ; Gas	Mole fraction - 3; Liquid	Temperature, K; Liquid	Gas Liquid	Density calibration data	13

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Thermophysical Study of the n-Hexane or n-Heptane with 1- Chloropropane Systems

Alonso, E.[Enrique], Guerrero, H.[Hernando], Montano, d.[diego], Lafuente, C.[Carlos], Artigas, H.[Hector]

ABSTRACT