ABSTRACT

Densities of the binary mixtures consist of methanol, ethanol, 1-propanol, 1-butanol and 1-pentanol with diisopropylamine were measured at temperatures (293.15, 298.15, 303.15 and 313.15) K and atmospheric pressure. Data were used to calculate the excess molar volumes. All the excess molar volumes are large and negative over the whole range of mole fraction, indicating strong interactions between unlike molecules. The ERAS-model has been applied for describing the binary excess molar volumes. The ERAS parameters confirm that the strong interactions between unlike molecules are encountered in mixtures. Also The Peng Robinson Stryjek Vera (PRSV) equation of state has been used to predict the binary excess molar volumes.

Compounds

#	Formula	Name
1	C6H15N	diisopropylamine
2	CH4O	methanol
3	C2H6O	ethanol
4	C3H8O	propan-1-ol
5	C4H10O	butan-1-ol
6	C5H12O	pentan-1-ol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	4
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	48
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	48
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	48
POMD	5 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	48
POMD	6 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	48

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Excess molar volumes of Diisopropylamine + (C1-C5) Alkan-1-ols: application of the ERAS model and cubic EOS

Almasi, M.[Mohammad], Shojabakhtiar, M.[Maryam]

ABSTRACT