ABSTRACT

Partial and integral enthalpies of mixing of liquid ternary In-Sn-Zn alloys were determined at 500deg C along seven sections over a large composition range. Additionally, binary alloys of the constituent system In-Sn were investigated at the same temperature. The measurements were carried out using a Calvet-type microcalorimeter and a drop calorimetric technique. The binary data were evaluated by means of a standard Redlich-Kister polynomial fit whereas ternary data were fitted on the basis of an extended Redlich-Kister-Muggianu model for substitutional solutions.

Compounds

#	Formula	Name
1	In	indium
2	Sn	tin
3	Zn	zinc

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	10
POMD	2 3 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 2; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	76
POMD	2 3 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	46

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Enthalpies of Mixing of Liquid In-Sn and In-Sn-Zn Alloys

Rechchach, M., Sabbar, A., Flandorfer, H., Ipser, H.

ABSTRACT