ABSTRACT

Excess molar enthalpies at 303.15 K have been determined for binary liquid mixtures of dibromomethane (CH2Br2) (DBM) with acetonitrile,furan and acetophenone.The excess molar enthalpies for the systems are endothermic for CH2Br2 + acetonitrile,and +furan whereas exothermic for the system CH2Br2 + acetophenone in nature. The excess partial molar enthalpies of the components have also been evaluated.These results indicate the existence of specific interactions between all these components. Key wwwwwwwords: Excess enthalpy,Microcalorimeter,Partial Molar Excess Enthalpy,Dibromomethane

Compounds

#	Formula	Name
1	CH2Br2	dibromomethane
2	C4H4O	furan
3	C2H3N	acetonitrile
4	C8H8O	acetophenone

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 3	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	8
POMD	1 2	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	8
POMD	1 4	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	8

Thermodynamics Research Center / ThermoML | Thermochimica Acta

EXCESS MOLAR ENTHALPIES OF DIBROMOMETHANE WITH ACETONITRILE,FURAN AND ACETOPHENONE 303.15 K

Tripathi, A. D.[Atri D.]

ABSTRACT