ABSTRACT

The enthalpies of dilution of aqueous solutions of N-acetyl-N -methyl-l-glycinamide (AcGlyNHCH3), N-acetyl-N -methyl-l- -alaninamide (AcAlaNHCH3),N-acetyl-N -methyl-l- -valinamide (AcValNHCH3), N-acetyl-N -methyl-l- -leucinamide (AcLeuNHCH3) (BACHEM) and N-acetyl-N -methyl-l- -serinamide (AcSerNHCH3), N-acetyl-N -methyl-l- -threoninamide (AcThrNHCH3), in water at 298.15K have been measured. These data were used to calculate the homogeneous enthalpic pair interaction coefficients based on McMillan Mayer s theory.

Compounds

#	Formula	Name
1	C6H12N2O2	(S)-2-acetamido-N-methylpropanamide
2	C5H10N2O2	2-acetamido-N-methylacetamide
3	C8H16N2O2	N-acetyl-N'-methylvalinamide
4	C9H18N2O2	(S)-2-acetamido-N,4-dimethylpentanamide
5	C6H12N2O3	N-acetyl-N'-methyl-l-alpha-serinamide
6	C7H14N2O3	N-acetyl-N'-methyl-L-alpha-threoninamide
7	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	5	Normal melting temperature, K ; Crystal			Crystal Liquid Air at 1 atmosphere	Resistive pulse heating	1
POMD	6	Normal melting temperature, K ; Crystal			Crystal Liquid Air at 1 atmosphere	Resistive pulse heating	1
POMD	7 1	Molar enthalpy of dilution, kJ/mol ; Liquid	Initial molality of solute, mol/kg; Liquid Final molality of solute, mol/kg; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Isothermal calorimeter	11
POMD	2 7	Molar enthalpy of dilution, kJ/mol ; Liquid	Initial molality of solute, mol/kg; Liquid Final molality of solute, mol/kg; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Isothermal calorimeter	13
POMD	7 3	Molar enthalpy of dilution, kJ/mol ; Liquid	Initial molality of solute, mol/kg; Liquid Final molality of solute, mol/kg; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Isothermal calorimeter	14
POMD	7 4	Molar enthalpy of dilution, kJ/mol ; Liquid	Initial molality of solute, mol/kg; Liquid Final molality of solute, mol/kg; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Isothermal calorimeter	13
POMD	7 5	Molar enthalpy of dilution, kJ/mol ; Liquid	Initial molality of solute, mol/kg; Liquid Final molality of solute, mol/kg; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Isothermal calorimeter	13
POMD	7 6	Molar enthalpy of dilution, kJ/mol ; Liquid	Initial molality of solute, mol/kg; Liquid Final molality of solute, mol/kg; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Isothermal calorimeter	13

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Studies of homogeneous interactions of N-acetyl-N-methyl-l-amino acid amides in water at 298.15

Palecz, B.[Bartlomiej], Belica, S.[Sylwia], Piekarski, H.[Henryk], Jozwiak, A.[Andrzej]

ABSTRACT